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Merck
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重要文件

422363

Sigma-Aldrich

双乙烯酮

contains copper sulfate as stabilizer

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About This Item

經驗公式(希爾表示法):
C4H4O2
CAS號碼:
分子量::
84.07
Beilstein:
104541
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
暫時無法取得訂價和供貨情況

蒸汽密度

2.9 (vs air)

蒸汽壓力

7.9 mmHg ( 20 °C)

形狀

liquid

自燃溫度

590 °F

包含

copper sulfate as stabilizer

折射率

n20/D 1.439 (lit.)

bp

69-70 °C/100 mmHg (lit.)

密度

1.09 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C=C1CC(=O)O1

InChI

1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2

InChI 密鑰

WASQWSOJHCZDFK-UHFFFAOYSA-N

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應用

用于乙酰乙酸衍生物和杂环化合物的简易制备。[1]

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

93.2 °F - closed cup

閃點(°C)

34 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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R Scandurra et al.
FEBS letters, 231(1), 192-196 (1988-04-11)
Horse liver phosphopantothenoylcysteine decarboxylase (EC 4.1.1.36) is rapidly inactivated by N-acetoacetylation with diketene following a pseudo-first-order kinetics: the presence of substrate quantitatively protects against this inactivation. Histidine photo-oxidation with methylene blue or rose bengal brings about the total loss of
P Roch et al.
Biochimica et biophysica acta, 983(2), 193-198 (1989-08-07)
The hemolytic activity exhibited by the coelomic fluid of the Annelid Eisenia fetida andrei is mediated by two lipoproteins of mass 40 and 45 kDa, each of them capable of hemolysis. Such an activity is not inhibited by zymosan, inulin
K Tanizawa et al.
Chemical & pharmaceutical bulletin, 37(3), 824-825 (1989-03-01)
Compounds having a structural analogy with diketene have been synthesized and their potencies as beta-lactamase inhibitors have been studied. Among six compounds so far tested, alpha-phenyl-beta-benzylidene-3-propanolide was shown to be an irreversible inhibitor of the enzyme. The availability of simple
A Fotedar et al.
Clinical and experimental immunology, 49(2), 317-324 (1982-08-01)
Two acetoacetylated derivatives of Mycobacterium leprae with variable hapten groups and a conjugate with tetanus toxoid were prepared. These were tested as antigens along with unmodified M. leprae in the leucocyte migration inhibition response of leucocytes from clinically, bacteriologically and
Atieh Rezvanian et al.
Molecular diversity, 24(4), 1313-1325 (2019-10-03)
Novel and efficient multicomponent reactions (MCRs) involving diketene, ninhydrin (indane-1,2,3-trione) and one primary amine (3CR) or two different primary amines (4CR) were achieved for the successful synthesis of dihydro-4H-indeno[1,2-b]furan-3-carboxamides or tetrahydroindeno[1,2-b]pyrrole-3-carboxamides, respectively. The merits of this method are highlighted by

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