421804

(1S,2S)-反式-1,2-环己二醇

99%

• 同義詞: (1S)-反-1,2-环己二醇
• 線性公式: C₆H₁₀(OH)₂
• CAS號碼: 57794-08-8
• 分子量：: 116.16
• Beilstein: 1901343
• MDL號碼: MFCD00066431
• 分類程式碼代碼: 12352001
• PubChem物質ID: 24866402
• NACRES: NA.22

屬性

• 化驗: 99%
• 光學活性: [α]20/D +39°, c = 1.6 in H₂O
• 光學純度: ee: 99% (GLC)
• mp: 107-109 °C (lit.)
• 官能基: hydroxyl
• SMILES 字串: O[C@H]1CCCC[C@@H]1O
• InChI: 1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6-/m0/s1
• InChI 密鑰: PFURGBBHAOXLIO-WDSKDSINSA-N

描述

應用

C₂-对称手性二醇，具有多种用途如手性助剂、[1][2]结构单元[3][4][5]和手性配体。[6][7]

(1S,2S)-trans-1,2-Cyclohexanediol may be used in the preparation of (1S,2S)-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride.[8] It may also be used as a chiral ligand for the preparation of non-racemic hydroxy phosphonates via titanium alkoxide-catalyzed addition of dimethyl phosphite to the corresponding aldehydes.[9]

安全資訊

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H318,H335
• 防範說明: P261 - P280 - P305 + P351 + P338
• 危險分類: Eye Dam. 1 - STOT SE 3
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves