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重要文件

41413

Sigma-Aldrich

2,6-二甲基苯基异腈

≥98.0% (GC)

同義詞:

连间二甲苯基异腈

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About This Item

線性公式:
(CH3)2C6H3NC
CAS號碼:
分子量::
131.17
Beilstein:
3541909
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

≥98.0% (GC)

形狀

powder

mp

72-75 °C

儲存溫度

2-8°C

SMILES 字串

Cc1cccc(C)c1[N+]#[C-]

InChI

1S/C9H9N/c1-7-5-4-6-8(2)9(7)10-3/h4-6H,1-2H3

InChI 密鑰

DNJLFZHMJDSJFN-UHFFFAOYSA-N

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應用

2,6-Dimethylphenyl isocyanide may be employed for the synthesis of homoleptic metallaamidine complex, Mo(η2-Me2NCN-2,6-C6H3)4, via reaction with Mo(NMe2)4.[1]

其他說明

综述[2]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Carbon-nitrogen bond formation in the reaction between tetrakis(dimethylamido)molybdenum(IV) and 2,6-dimethylphenyl isocyanide. Preparation and characterization of the first homoleptic metallaamidine complex: Mo(.eta.2-Me2NC:NC6H3Me3-2,6)4.
M H Chisholm et al.
Journal of the American Chemical Society, 108(24), 7860-7861 (1986-11-01)
Reactions of (Me3ECH2) 3ZrSi (SiMe3) 3 (E= C, Si) with 2, 6-Dimethylphenyl Isocyanide. Preferential Isocyanide Insertion into Zr-Silyl Bonds.
Wu Z, et al.
Organometallics, 17(22), 4853-4860 (1998)
Surface Enrichment of Ag Atoms in Au/Ag Alloy Nanoparticles Revealed by Surface-Enhanced Raman Scattering of 2, 6-Dimethylphenyl Isocyanide.
Kim K, et al.
The Journal of Physical Chemistry C, 114(8), 3448-3453 (2010)
M.P. Periassamy et al.
Organic preparations and procedures international, 11, 295-295 (1979)
M A Wood et al.
The Biochemical journal, 247(3), 675-678 (1987-11-01)
A series of aromatic isonitriles were synthesized and their binding to sheep haemoglobin and horse heart myoglobin was investigated. The disubstituted ligands 2,6-dimethylphenylisonitrile and 2,6-diethylphenylisonitrile were found to bind to horse-heart myoglobin with affinities ranging from 500 to 5000 times

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