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410551

2,6-二氯-4-(三氟甲基)苯肼

Name: 2,6-二氯-4-(三氟甲基)苯肼
Brand: ALDRICH

98%

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About This Item

線性公式:

Cl₂C₆H₂(CF₃)NHNH₂

CAS號碼:

86398-94-9

分子量：:

245.03

MDL號碼:

MFCD00085001

分類程式碼代碼:

12352100

PubChem物質ID:

24865533

NACRES:

NA.22

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化驗

98%

mp

58-60 °C (lit.)

SMILES 字串

NNc1c(Cl)cc(cc1Cl)C(F)(F)F

InChI

1S/C7H5Cl2F3N2/c8-4-1-3(7(10,11)12)2-5(9)6(4)14-13/h1-2,14H,13H2

InChI 密鑰

FYOWOHMZNWQLFG-UHFFFAOYSA-N

一般說明

[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine is a hydrazine derivative.[1] It reacts with excess of ethyl acetoacetate to afford 1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3,4-dimethylpyrano[2,3-c]pyrazol-6(1H)-one.[2]

應用

[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine may be used for the synthesis of pyrazolo[4,3-d]isoxazole derivatives.[1] It may also be used in the synthesis of following N-(2,6-dichloro-4-trifluoromethyl)phenyl-N′-(1-phenylethylidene) hydrazines:[3]

N-(2,6-dichloro-4-trifluoromethyl)phenyl-N′-(1-phenylethylidene)hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(4-chlorophenyl)ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(3-chlorophenyl)ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(4-bromophenyl)-ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(3-bromophenyl)ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(4-methoxyphenyl)ethylidene]-hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(4-trifluoromethylphenyl)-ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(4-nitrophenyl)ethylidene]hydrazine
N-(2,6-Dichloro-4-trifluoromethyl)phenyl-N′-[1-(6-methoxy-naphthalen-2-yl)-ethylidene]hydrazine

象形圖

GHS08,GHS07

訊號詞

Warning

危險聲明

H302 + H312 + H332,H315,H319,H335,H351

防範說明

P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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分析證明 (COA)

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Synthesis of novel 1-[(2,6-dichloro-4-trifluoromethyl)phenyl]-3-aryl-1H-pyrazole-4-carbaldehydes.

Huanan Hu et al.

Molecules (Basel, Switzerland), 15(10), 7472-7481 (2010-10-27)

A series of novel 1-[(2,6-dichloro-4-trifluoromethyl)phenyl]-3-aryl-¹H-pyrazole-4-carbaldehydes were synthesized using the Vilsmeier-Haack reagent. The structures of all the title compounds have been confirmed by elemental analysis, ¹H-NMR and ¹³C-NMR and in addition, the structure of intermediate 5b was investigated by X-ray crystallography.

SYNTHESIS AND ANTIBACTERIAL ACTIVITY OF FUSED ISOXAZOLE DERIVATIVES USING GRINDING METHOD.

Badrey MG and Gomha SM.

International Journal of Pharmacy and Pharmaceutical Sciences, 6(7) (2014)

1-[2,6-Dichloro-4-(trifluoro-meth-yl)phen-yl]-3,4-dimethyl-pyrano[2,3-c]pyrazol-6(1H)-one.

Hoong-Kun Fun et al.

Acta crystallographica. Section E, Structure reports online, 68(Pt 8), o2350-o2350 (2012-08-21)

In the title compound, C(15)H(9)Cl(2)F(3)N(2)O(2), the 1,6-dihydro-pyrano[2,3-c]pyrazole ring system is almost planar, with a maximum deviation of 0.0226 (14) Å, and forms a dihedral angle of 69.90 (6)° with the benzene ring. In the crystal, mol-ecules are linked into a helical chain along

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