391638
二甲基氯化磷胺
97%
同義詞:
(Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride
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About This Item
線性公式:
(CH3)2NPCl2
CAS號碼:
分子量：:
145.96
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
97%
形狀
liquid
折射率
n20/D 1.505 (lit.)
bp
150 °C (lit.)
密度
1.271 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CN(C)P(Cl)Cl
InChI
1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
InChI 密鑰
XPWWDZRSNFSLRQ-UHFFFAOYSA-N
一般說明
Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.
應用
Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
- N,N-dimethylamidotetrachlorophosphorane
- O-propylchloroformimino-N,N-dimethylamidochlorophosphate
- 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
-9.4 °F - closed cup
閃點（°C）
-23 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
客戶也查看了
G K Surya Prakash et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(36), 15693-15698 (2010-08-21)
It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologically important organic molecules with fluorine are of great interest to
35Cl NQR spectra of phosphorus chlorides and their molecular conformations in crystals. Part 1. Phosphorus (III) chlorides RPCl2.
Kozlov ES, et al.
Journal of Molecular Structure, 550, 167-175 (2000)
Reaction of 1, 1-dichloro-1-nitrosobutane with N, N-dimethylamidodichlorophosphite.
Sokolov VB, et al.
Bulletin of the Academy of Sciences of the USSR, Division of chemical science, 38(6), 1296-1298 (1989)
Reactions of sulfur dioxide with aminophosphines.
Light RW and Paine RT.
Phosph. Sulfur Relat. Elem., 8(3), 255-258 (1980)
Equilibrium conformation of dimethylaminodichlorophosphine molecule: the use of the results of quantum-chemical calculations and spectroscopic measurements in the analysis of gas-phase electron diffraction data.
Khaikin LS, et al.
Russian Chemical Bulletin, 50(9), 1550-1562 (2001)
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