推薦產品
化驗
99%
形狀
liquid
折射率
n20/D 1.558 (lit.)
bp
70-72 °C/0.7 mmHg (lit.)
密度
1.075 g/mL at 25 °C (lit.)
SMILES 字串
CC1CC(=O)c2ccccc12
InChI
1S/C10H10O/c1-7-6-10(11)9-5-3-2-4-8(7)9/h2-5,7H,6H2,1H3
InChI 密鑰
XVTQSYKCADSUHN-UHFFFAOYSA-N
一般說明
3-Methyl-1-indanone is a derivative of 1-indanone.Its synthesis has been reported. The 1H and 13C-NMR spectra of 3-methyl-1-indanone has been reported. Biocatalyzed oxidation of racemic 3-methyl-1-indanone with high enanatioselectivity has been investigated.
應用
3-Methyl-1-indanone is suitable for the synthesis of branched alkyl indanes (BINs). It may be used in the following studies:
- Synthesis of 2,2,3-tribromo-2,3-dihydro-3-methylinden-1-one and 2-bromo-3-bromomethyl-1H-inden-1-one.
- As photosensitizers for the splitting of dimethylthymine dimers.
- As a model to verify three-phase model in enantioselective gas-liquid chromatography.
- (-)-(R)-3-methyl-1-indanone may be used as standard for comparing the optical rotatory dispersion curve with 1,3-dialkylindenes in the study of base-catalyzed 1,3 proton transfer in indene systems.
- As an optically active sensitizer to induce asymmetry in trans-1,2-diphenylcylcopropane (DPC).
- The dl-isomers of 3-methyl-1-indanone may be used in the synthesis of monomeric and trimeric 3-methyl-1-indanethione.
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
Asymmetric induction during transfer of triplet energy.
Ouannes C, et al.
Journal of the American Chemical Society, 95(25), 8472-8474 (1973)
Thiocarbonyls. VI. Studies in the Indanone and Tetralone Series1.
Campaigne E and Moss RD.
Journal of the American Chemical Society, 76(5), 1269-1271 (1954)
Ana Rioz-Martínez et al.
The Journal of organic chemistry, 75(6), 2073-2076 (2010-02-20)
Baeyer-Villiger monooxygenases have been tested in the oxidation of racemic benzofused ketones. When employing a single mutant of phenylacetone monooxygenase (M446G PAMO) under the proper reaction conditions, it was possible to achieve 3-substituted 3,4-dihydroisocoumarins with high yields and optical purities
Electrophilic substitution at saturated carbon. XLIII. Alkylammonium carbanide ion-pair reorganization reactions in base-catalyzed 1,3-proton transfer in an indene system.
Almy J and Cram DJ.
Journal of the American Chemical Society, 91(16), 4459-4468 (1969)
Photochemistry of ketones in solution--49. A study of photosensitized splitting of dimethylthymine dimers.
D I Schuster et al.
Photochemistry and photobiology, 25(3), 239-242 (1977-03-01)
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