![[Ir(cod)(acac)] Umicore](/deepweb/assets/sigmaaldrich/product/structures/188/615/470bfca9-6b61-476a-9486-f7da61962e4c/640/470bfca9-6b61-476a-9486-f7da61962e4c.png)
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
About This Item
推薦產品
化驗
97%
形狀
powder
反應適用性
core: iridium
reagent type: catalyst
mp
160-165 °C (dec.) (lit.)
SMILES 字串
Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
InChI
1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI 密鑰
WBRREXQCZAFSKS-XFCUKONHSA-L
應用
- 作为稳定剂，与 nido- carboranyldiphosphine 发生异构化-硼氢化反应。[1]
- 过氧化氢氧化异羟肟酸，及其随后的杂环 Diels-Alder 环加成反应。[2]
- 通过乙烯基硅烷偶联反应将有机官能团固定在固体载体上。[3]
- 烷基化反应。[4]
- 格柏反应。[5]
- 使用 DNA-二烯-铱（I）杂化体系的烯丙基胺化反应。[6]
- 不对称的加氢胺化反应。[7]
- 以 nido- carboranyldiphosphine 作为稳定配体的异构化-硼氢化反应
- 过氧化氢氧化异羟肟酸及其随后的杂 Diels-Alder 环加成反应
- 通过乙烯基硅烷偶联反应将有机官能团固定在固体载体上
- 烷基化反应
- 格柏反应
- DNA-二烯-铱（I）杂化体系中的烯丙基胺化反应
- 不对称的加氢胺化反应
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
客戶也查看了
文章
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
-
How can I determine the shelf life / expiration / retest date of this product?
1 answer-
Helpful?
-
-
How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Helpful?
-
Active Filters
我們的科學家團隊在所有研究領域都有豐富的經驗，包括生命科學、材料科學、化學合成、色譜、分析等.
聯絡技術服務
