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Merck
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369071

Sigma-Aldrich

2-溴-4,5-二氟苯酚

99%

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About This Item

線性公式:
BrC6H2(F)2OH
CAS號碼:
分子量::
208.99
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.531 (lit.)

密度

1.829 g/mL at 25 °C (lit.)

SMILES 字串

Oc1cc(F)c(F)cc1Br

InChI

1S/C6H3BrF2O/c7-3-1-4(8)5(9)2-6(3)10/h1-2,10H

InChI 密鑰

FCYZOOHWUOEAOX-UHFFFAOYSA-N

一般說明

2-Bromo-4,5-difluorophenol is reported to undergo palladium-catalyzed cyclotrimerization to yield hexafluoro- and trimethoxytriphenylene derivatives.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

177.8 °F - closed cup

閃點(°C)

81 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Efficient Palladium-Catalyzed Cyclotrimeriza-tion of Arynes: Synthesis of Triphenylenes
PenAa D, et al.
Angewandte Chemie (International Edition in English), 37 (1998)
Yi-Lin Liu et al.
The Journal of organic chemistry, 74(8), 3199-3202 (2009-03-20)
Palladium-catalyzed cocyclotrimerization of allenes with arynes has been developed for selectively synthesizing phenanthrenes. In the presence of [(allyl)PdCl](2) and P(o-tol)(3), a variety of allenes, including internal and terminal allenes, underwent the cocyclotrimerization with arynes to afford the corresponding phenanthrenes in

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