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重要文件

365157

Sigma-Aldrich

1,1,3,3-四甲基-1,3-二苯基二硅胺烷

96%

同義詞:

1,3-联苯基四甲基二硅氮烷, DPTMDS

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About This Item

線性公式:
[C6H5Si(CH3)2]2NH
CAS號碼:
分子量::
285.53
Beilstein:
2738118
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

96%

形狀

liquid

折射率

n20/D 1.538 (lit.)

bp

96-100 °C/0.1 mmHg (lit.)

密度

0.985 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(N[Si](C)(C)c1ccccc1)c2ccccc2

InChI

1S/C16H23NSi2/c1-18(2,15-11-7-5-8-12-15)17-19(3,4)16-13-9-6-10-14-16/h5-14,17H,1-4H3

InChI 密鑰

HIMXYMYMHUAZLW-UHFFFAOYSA-N

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應用

1,1,3,3-Tetramethyl-1,3-diphenyldisilazane can be used:
  • As a starting material for the synthesis of its substitution products with the tetrachlorides of silicon and tin.[1]
  • To prepare Cu-, Zn- and H2-phthalocyanines using phthalimide.[2]
  • As a pre-column deactivation agent prior to the determination of the fatty acids by GC-MS.[3]

象形圖

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訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Silazanes plus MCl4-substitution vs. rearrangement reactions
Lehnert C, et al.
Chemistry of Heterocyclic Compounds, 42(12), 1574-1584 (2006)
Convenient synthesis of phthalocyanines with disilazanes under mild conditions.
Uchida H, et al.
ARKIVOC (Gainesville, FL, United States), 11, 17-23 (2005)
Dorothee Eibler et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1046, 138-146 (2017-02-10)
Between 2008 and 2011, four polar bears (Ursus maritimus) from the Greenland population swam and/or drifted on ice to Iceland where they arrived in very poor body condition. Body fat resources in these animals were only between 0% and 10%
Simon Hammann et al.
Analytical and bioanalytical chemistry, 407(30), 9019-9028 (2015-10-07)
Triacylglycerols represent the major part (>90%) in most plant oils and have to be eliminated, when the minor compounds such as phytosterols or tocopherols should be analyzed. Here, we used an all liquid-liquid chromatographic technique, countercurrent chromatography (CCC), to fractionate

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