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362883

Sigma-Aldrich

二苄基 N,N-二乙基亚磷酰胺

technical grade, 85%

同義詞:

TTC

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About This Item

線性公式:
(C2H5)2NP(OCH2C6H5)2
CAS號碼:
67746-43-4
分子量：:
317.36
Beilstein:
4189915
MDL號碼:
MFCD00191987
分類程式碼代碼:
12352100
PubChem物質ID:
24862337
NACRES:
NA.22

等級

technical grade

蒸汽壓力

0.71 psi ( 55 °C)

化驗

85%

形狀

liquid

折射率

n20/D 1.545 (lit.)

密度

1.06 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCN(CC)P(OCc1ccccc1)OCc2ccccc2

InChI

1S/C18H24NO2P/c1-3-19(4-2)22(20-15-17-11-7-5-8-12-17)21-16-18-13-9-6-10-14-18/h5-14H,3-4,15-16H2,1-2H3

InChI 密鑰

NLGUJOVLAXLSMX-UHFFFAOYSA-N

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相關類別

一般說明

据报道，二苄基N,N-二乙基亚磷酰胺是受保护丝氨酸衍生物的高效的 1H-四唑催化′亚磷酸三酯′磷酸化的合适试剂。

應用

二苄基 N,N-二乙基亚磷酰胺可用于：
  • 在糖基亚磷酸酯和磷酸酯的合成中作为亚磷酸化试剂。
  • 醇的亚磷酸化
  • 制备in the preparation of 6-二苄基磷酸-1,3,5-三-O-PMB--肌醇

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

93.2 °F - closed cup

閃點（°C）

34 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析證明 (COA)

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Peter A Jordan et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(48), 20620-20624 (2010-05-05)
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Perich JW and Johns RB.
Australian Journal of Chemistry, 43(10), 1623-1632 (1990)
Synthesis of dibenzyl glycosyl phosphites using dibenzyl N, N-diethylphosphoramidite as phosphitylating reagent: an effective route to glycosyl phosphates, nucleotides, and glycosides.
Sim MM, et al.
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Acta pharmacologica Sinica, 40(10), 1314-1321 (2019-05-08)
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