推薦產品
化驗
99%
折射率
n20/D 1.525 (lit.)
bp
90 °C/1 mmHg (lit.)
密度
1.215 g/mL at 25 °C (lit.)
官能基
chloro
ester
phenyl
SMILES 字串
ClCC(=O)OCc1ccccc1
InChI
1S/C9H9ClO2/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5H,6-7H2
InChI 密鑰
SOGXBRHOWDEKQB-UHFFFAOYSA-N
一般說明
Benzyl chloroacetate is an ester.
應用
Benzyl chloroacetate may be used:
- in the synthesis of monoesters of phosphonoacetic acid[1]
- in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis[2]
- as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E[3]
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Influence of the substrate structure on carboxypeptidase Y catalyzed peptide bond formation.
Breddam K, et al.
Carlsberg Research Communications, 45(5), 361-367 (1980)
T R Herrin et al.
Journal of medicinal chemistry, 20(5), 660-663 (1977-05-01)
The synthesis of monoesters (P and C) of phosphonoacetic acid (PA) is given. The carboxyl esters were prepared by two methods: the reaction of chloroacetates with tris(trimethylsilyl) phosphite, followed by hydrolysis; and by the acid-catalyzed esterification of PA with the
Stereoselective total syntheses of the (?)-di-O-methyl ethers of agatharesinol, sesquirin-A, and hinokiresinol, and of (?)-tri-O-methylsequirin-E, characteristic norlignans of coniferae.
Beracierta AP and Whiting DA.
Journal of the Chemical Society. Perkin Transactions 1, 10, 1257-1263 (1978)
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