跳轉至內容
Merck
全部照片(1)

重要文件

349461

Sigma-Aldrich

4-甲氧基吡啶 N-氧化物 水合物

97%

登入查看組織和合約定價


About This Item

經驗公式(希爾表示法):
C6H7NO2 · xH2O
CAS號碼:
分子量::
125.13 (anhydrous basis)
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
暫時無法取得訂價和供貨情況

化驗

97%

mp

82-85 °C (lit.)

SMILES 字串

[H]O[H].COc1cc[n+]([O-])cc1

InChI

1S/C6H7NO2.H2O/c1-9-6-2-4-7(8)5-3-6;/h2-5H,1H3;1H2

InChI 密鑰

ABJMARLKAXBQBC-UHFFFAOYSA-N

一般說明

4-Methoxypyridine N-oxide hydrate is a substituted pyridine N-oxide. It forms 1:1 complexes with MnCl2 and NiCl2 salts.[1] Mechanism of reaction between 4-methoxypyridine N-oxide hydrate and bis(pinacolato) (diboron reagent) in CD3CN has been studied by NMR.[2] It forms 1:1 complex with 2,4-dinitrophenol due to the formation of intermolecular hydrogen bond between the O-H and N-O groups.[3]

應用

4-Methoxypyridine N-oxide hydrate may be used in chemical synthesis.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Hari Prasad Kokatla et al.
The Journal of organic chemistry, 76(19), 7842-7848 (2011-08-05)
Facile reduction of alkylamino-, anilino-, and pyridyl-N-oxides can be achieved via the use of diboron reagents, predominantly bis(pinacolato)- and in some cases bis(catecholato)diboron [(pinB)(2) and (catB)(2), respectively]. Reductions occur upon simply mixing the amine N-oxide and the diboron reagent in
1: 1 Complex of 2, 4-dinitrophenol and 4-methoxypyridine N-oxide hydrate.
Moreno-Fuquen R, et al.
Acta Crystallographica Section E, Structure Reports Online, 57(8), o712-o714 (2001)
Binuclear chlorine-bridged complexes of manganese (II) and nickel (II) chlorides with pyridine N-oxides.
Karayannis NM, et al.
Inorganic Chemistry, 8(12), 2559-2562 (1969)

Questions

Reviews

No rating value

Active Filters

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務