跳轉至內容
Merck
全部照片(1)

重要文件

338389

Sigma-Aldrich

三苯基膦氢溴酸盐

97%

同義詞:

Ph3P · HBr, Ph3P · HBr, 三苯基溴化膦

登入查看組織和合約定價


About This Item

線性公式:
(C6H5)3P · HBr
CAS號碼:
分子量::
343.20
Beilstein:
3633387
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

化驗

97%

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

mp

196 °C (dec.) (lit.)

官能基

phosphine

SMILES 字串

Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H

InChI 密鑰

CMSYDJVRTHCWFP-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

應用

用作无水氢溴酸的温和来源;从叔醇合成 THP 醚的催化剂; 磷盐制备。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

客戶也查看了

Slide 1 of 2

1 of 2

Hamanaka, N.; Kosuge, S.; Iguchi, S.
Synlett, 139-139 (1990)
Kaila, N.; Blumenstein, M. et al.
The Journal of Organic Chemistry, 57, 4576-4576 (1992)
Tong Wang et al.
Organic & biomolecular chemistry, 9(14), 5260-5265 (2011-06-02)
The triphenylphosphine-catalyzed formal [3 + 2] cycloaddition of allenoates and trifluoromethylketones was realized to give the corresponding dihydrofurans in good yields with excellent γ-regioselectivities. Hydrogenation of the dihydrofurans gave 2,4,4-trisubstituted tetrahydrofurans in good yields with exclusive cis-selectivities.
Yong Ma et al.
Langmuir : the ACS journal of surfaces and colloids, 27(21), 13097-13103 (2011-09-21)
Chemically selective liposomal surface functionalization and liposomal microarray fabrication using azide-reactive liposomes are described. First, liposome carrying PEG-triphenylphosphine was prepared for Staudinger ligation with azide-containing biotin, which was conducted in PBS buffer (pH 7.4) at room temperature without a catalyst.
Kirill Nikitin et al.
Chemical communications (Cambridge, England), 49(14), 1434-1436 (2013-01-17)
Triphenylhalophosphonium halides, Ph(3)PX(2), form crystals comprising bridged linear cations [Ph(3)P-X-X-X-PPh(3)](+) where the X(3) bridge is shortened from 6.56 Å in Cl-Cl-Cl to 6.37 Å in the Br-Br-Br system. It is proposed that this structure is stabilised by five-centre/six-electron (5c-6e) hypervalent

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務