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Merck
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文件

335568

Sigma-Aldrich

2-甲氧基-2-苯乙醇

99%

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About This Item

線性公式:
C6H5CH(OCH3)CH2OH
CAS號碼:
2979-22-8
分子量：:
152.19
EC號碼:
221-030-2
MDL號碼:
MFCD00075063
分類程式碼代碼:
12352100
PubChem物質ID:
24860327
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.519 (lit.)

bp

237 °C (lit.)

密度

1.061 g/mL at 25 °C (lit.)

SMILES 字串

COC(CO)c1ccccc1

InChI

1S/C9H12O2/c1-11-9(7-10)8-5-3-2-4-6-8/h2-6,9-10H,7H2,1H3

InChI 密鑰

JDTUPLBMGDDPJS-UHFFFAOYSA-N

應用

(S)-2-methoxy-2-phenylethanol was employed as chiral probe for the determination of absolute configuration of active (-) enantiomer of amlodipine. 2-Methoxy-2-phenylethanol was also used in the synthesis of optically active 1,4-dihydropyridines.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

208.4 °F - closed cup

閃點（°C）

98 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析證明 (COA)

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Enzymatic resolution of the chiral inductor 2-methoxy-2-phenylethanol.
Monterde MI, et al.
Tetrahedron Asymmetry, 13(10), 1091-1096 (2002)
S Goldmann et al.
Journal of medicinal chemistry, 35(18), 3341-3344 (1992-09-04)
The active (-) enantiomer of amlodipine was originally reported to have R configuration. This does not concur with other 1,4-dihydropyridines with known absolute configuration. This configuration has now been determined by X-ray structural analysis using (1S)-camphanic acid and (S)-2-methoxy-2-phenylethanol as

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