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308188

Sigma-Aldrich

苯甲酰异氰酸酯

technical grade, 90%

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About This Item

線性公式:
C6H5CONCO
CAS號碼:
分子量::
147.13
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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等級

technical grade

化驗

90%

折射率

n20/D 1.5514 (lit.)

bp

94-96 °C/21 mmHg (lit.)

密度

1.171 g/mL at 25 °C (lit.)

官能基

amine
isocyanate
phenyl

儲存溫度

−20°C

SMILES 字串

O=C=NC(=O)c1ccccc1

InChI

1S/C8H5NO2/c10-6-9-8(11)7-4-2-1-3-5-7/h1-5H

InChI 密鑰

LURYMYITPCOQAU-UHFFFAOYSA-N

一般說明

研究了苯甲酰异氰酸酯与6-苄基-6-氮杂双环[2.2.1]庚-2-烯的反应机理[1]

應用

苯甲酰基异氰酸酯在固相支持的寡糖合成中用作低反应性羟基的封端试剂[2]

象形圖

Health hazardExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

161.6 °F - closed cup

閃點(°C)

72 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Xiangyang Wu et al.
The Journal of organic chemistry, 69(6), 1853-1857 (2004-04-03)
Solid-phase-supported oligosaccharide synthesis of a core N-glycan tetrasaccharide and of a trisaccharide containing the Galili antigen is reported. The synthesis is based on a hydroxymethylbenzyl benzoate spacer-linker system attached to the Merrifield resin, O-Fmoc-protected O-glycosyl trichloroacetimidates as glycosyl donors, and
Cong Zhang et al.
The journal of physical chemistry. A, 114(8), 2913-2919 (2010-02-09)
Reaction mechanisms of the 6-benzyl-6-azabicyclo[2.2.1]hept-2-ene with benzoyl isocyanate have been investigated using density functional theory (DFT) at the B3LYP/6-31G(d,p) level of theory. The reaction proceeding along six competitive channels includes two categories. That is, two channels are formally [3,3]-sigmatropic rearrangements
P Madhusudhana Reddy et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 186, 8-16 (2017-06-11)
Sensing of F

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