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重要文件

295086

Sigma-Aldrich

反式-2-丁烯

≥99%

同義詞:

β-反式丁烯, (2E)-2-丁烯, (E)-2-丁烯, 2-trans-丁烯, 2-反式丁烯, E-丁烯, 反丁烯, 反式-1,2-二甲基乙烯, 反式-2-丁烯

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About This Item

線性公式:
CH3CH=CHCH3
CAS號碼:
分子量::
56.11
Beilstein:
1718756
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度

2 (vs air)

品質等級

蒸汽壓力

2575 mmHg ( 37.7 °C)

化驗

≥99%

自燃溫度

615 °F

expl. lim.

9.7 %

bp

1 °C (lit.)

mp

−105 °C (lit.)

SMILES 字串

CC=CC

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI 密鑰

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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應用

反式-2-丁烯可用作单体单元,通过镍催化聚合反应产生具有既定微观结构的高分子量聚烯烃。也可用作异构化反应中的反应物,使用酸活化催化剂产生对应异构体。[1][2]

包裝

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。在使用气瓶前,务必确保阀门是关闭的,然后取下密封出口阀的镀锌钢六角螺帽。

兼容以下设备:

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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校準器

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軟管倒鉤

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象形圖

FlameGas cylinder

訊號詞

Danger

危險聲明

防範說明

危險分類

Flam. Gas 1 - Press. Gas Liquefied gas

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 3

閃點(°F)

-4.0 °F - closed cup

閃點(°C)

-20 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


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分析證明 (COA)

Lot/Batch Number

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Isomerization of cis-2-butene and trans-2-butene catalyzed by acid-and ion-exchanged smectite-type clays
Moronta A, et al.
Applied Clay Science, 29(2), 117-123 (2005)
Ni (II)-catalyzed polymerization of trans-2-butene
Leatherman MD and Brookhart M
Macromolecules, 34(9), 2748-2750 (2001)
Franz Worek et al.
Archives of toxicology, 86(9), 1379-1386 (2012-03-23)
The reactivation of organophosphorus compound (OP)-inhibited acetylcholinesterase (AChE) by oximes is inadequate in case of different OP nerve agents. This fact led to the synthesis of numerous novel oximes by different research groups in order to identify more effective reactivators.
Nadiya Bakhiya et al.
Archives of toxicology, 84(7), 563-578 (2010-03-20)
Furan is formed during commercial or domestic thermal treatment of food. The initial surveys of furan concentrations in heat-treated foods, published by European and US authorities, revealed the presence of relatively high furan levels in coffee, sauces, and soups. Importantly
Hao Ren et al.
The Journal of chemical physics, 133(6), 064702-064702 (2010-08-17)
Scanning tunneling microscopy (STM) topographical images and inelastic electron tunneling spectra (IETS) of a cis-2-butene molecule adsorbed on a Pd(110) surface have been simulated by first-principles calculations. Calculations have eliminated the ambiguity between the STM image and the adsorption orientation

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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