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文件

294071

Sigma-Aldrich

甲氧基甲基苯硫醚

97%

同義詞:

[(甲氧基甲基)硫基]苯

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About This Item

線性公式:
C6H5SCH2OCH3
CAS號碼:
分子量::
154.23
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

97%

折射率

n20/D 1.5632 (lit.)

bp

113-114 °C/18 mmHg (lit.)

密度

1.047 g/mL at 25 °C (lit.)

SMILES 字串

COCSc1ccccc1

InChI

1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI 密鑰

QPXQVNXSQCRWEV-UHFFFAOYSA-N

一般說明

Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.

應用

Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

203.0 °F - closed cup

閃點(°C)

95 °C - closed cup

個人防護裝備

Eyeshields, Gloves


分析證明 (COA)

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Solvent free permanganate oxidations.
Shaabani A and Lee DG.
Tetrahedron Letters, 42(34), 5833-5836 (2001)
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.
Maricich TJ and Harrington CK.
Journal of the American Chemical Society, 94(14), 5115-5116 (1972)
S P Hanlon et al.
Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)
The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic

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