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重要文件

293474

Sigma-Aldrich

4-溴-2-氟苯甲醚

97%

同義詞:

4-溴-2-氟-1-甲氧基苯

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About This Item

線性公式:
BrC6H3(F)OCH3
CAS號碼:
分子量::
205.02
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

97%

折射率

n20/D 1.545 (lit.)

bp

84 °C/7 mmHg (lit.)

密度

1.59 g/mL at 25 °C (lit.)

官能基

bromo
fluoro

SMILES 字串

COc1ccc(Br)cc1F

InChI

1S/C7H6BrFO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,1H3

InChI 密鑰

DWNXGZBXFDNKOR-UHFFFAOYSA-N

一般說明

The IR and FT-IR spectra of 4-bromo-2-fluoroanisole have been investigated[1].

應用

4-Bromo-2-fluoroanisole has been used in the synthesis of:
  • 1,4-bis[(3′-fluoro-4′-n alkoxyphenyl)ethynyl]benzenes with n=1-12[2]
  • 7-fluoro-6-methoxy-1-methyl-2-naphthaldehyde[3]
  • 5,7-difluoro-6-methoxy-1-methyl-2-naphthaldehyde[3]
  • liquid crystals with terminal difluoromethoxy group and backbone of phenylbicyclohexane[4]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

208.4 °F - closed cup

閃點(°C)

98 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Vibrational spectra, first hyperpolarizability, HOMO-LUMO analysis of 4-bromo 2-fluro anisole.
Arivazhagan M, et al.
Indian Journal of Pure and Applied Physics, 50(5), 299-307 (2012)
Design of molecular architectures for polymeric mesophase formation.
Pugh C, et al.
Macromolecular Symposia, 98(1) (1995)
Rolf W Hartmann et al.
Journal of enzyme inhibition and medicinal chemistry, 19(2), 145-155 (2004-09-29)
Regioselectively fluorinated 1-(naphth-2-ylmethyl)imidazoles 1a-h have been synthesized starting from the corresponding (naphth-2-yl)methanols (2). 2a-d have been obtained by LiAlH4-promoted reduction of fluorinated 1-methyl-2-naphthaldehydes. The latter were easily prepared in fairly good overall yields by ceric ammonium nitrate (CAN)-promoted oxidative addition
Syntheses of Phenylbicyclohexane Liquid Crystals with Terminal Difluoromethoxy Group [J].
Li J, et al.
Fine Chemicals / ????, 12, 004-004 (2004)

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