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重要文件

291390

Sigma-Aldrich

乙酸对甲苯酯

99%

同義詞:

乙酸对甲酚酯

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About This Item

線性公式:
CH3CO2C6H4CH3
CAS號碼:
分子量::
150.17
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

99%

折射率

n20/D 1.501 (lit.)

bp

210-211 °C (lit.)

密度

1.047 g/mL at 25 °C (lit.)

官能基

ester

SMILES 字串

CC(=O)Oc1ccc(C)cc1

InChI

1S/C9H10O2/c1-7-3-5-9(6-4-7)11-8(2)10/h3-6H,1-2H3

InChI 密鑰

CDJJKTLOZJAGIZ-UHFFFAOYSA-N

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一般說明

The Fries rearrangement of p-tolyl acetate has been investigated using the H-form of various zeolites as catalysts.[1] Mechanism of photo-Fries rearrangement of p-tolyl acetate has been studied.[2]

應用

p-Tolyl acetate has been used in the total synthesis of (−)-incrustoporin.[3]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

194.0 °F - closed cup

閃點(°C)

90 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Q Yu et al.
Journal of Asian natural products research, 1(3), 183-188 (2001-03-20)
(-)-Incrustoporin (1) has been synthesized using aldol condensation of ethyl p-tolyl-acetate (2) and (2R)-benzoyloxy-butanal (3), followed by acid-catalyzed deprotection of the benzoyl group, lactone ring-closure, and elimination of the beta-OH in a one-pot manner. The aldehyde 3 was prepared from
Mechanistic studies of the photo-Fries reaction.
Sandner MR, et al.
Journal of the American Chemical Society, 90(26), 7249-7254 (1968)
Fries rearrangement over zeolitic catalysts.
Vogt A, et al.
Applied Catalysis A: General, 123(1), 37-49 (1995)
Alfonso Pérez-Garrido et al.
Bioorganic & medicinal chemistry, 17(2), 896-904 (2008-12-06)
This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with beta-cyclodextrins (beta-CDs). Several different theoretical molecular descriptors, calculated solely from the molecular structure of the compounds under investigation

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量子點 (QDs):半導體奈米微粒,具有多樣化的應用,包括顯示器、照明和生物醫學成像。

Quantum dots (QDs): Semiconductor nanoparticles with diverse applications including displays, lighting, and biomedical imaging.

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