288403

反-二氯双(三苯基膦)铂(II)

• 同義詞: trans-Bis(triphenylphosphine)platinum dichloride
• 線性公式: [(C₆H₅)₃P]₂PtCl₂
• CAS號碼: 14056-88-3
• 分子量：: 790.56
• MDL號碼: MFCD00010825
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24857337
• NACRES: NA.22

屬性

• 反應適用性: core: platinum; reagent type: catalyst
• SMILES 字串: Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI 密鑰: XAFJSPPHVXDRIE-UHFFFAOYSA-L

描述

應用

Catalyst for:

• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
• Alkynylation and hydrogenation reactions
• Hetero-Diels-Alder/ring-opening reactions
• Insertion of carbenes into O-H bonds of alcohols
• Cyclopropanation of olefins
• Hydroformylation reactions

安全資訊

• 象形圖: GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H302,H315,H317,H319,H334,H335,H373
• 防範說明: P260 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 3
• 標靶器官: Central nervous system,Peripheral nervous system, Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves