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283606

Sigma-Aldrich

氯化钯(II) 溶液

5 wt. % in 10 wt. % HCl

同義詞:

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

線性公式:
PdCl2
CAS號碼:
分子量::
177.33
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

濃度

5 wt. % in 10 wt. % HCl

密度

1.06 g/mL at 25 °C

SMILES 字串

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI 密鑰

PIBWKRNGBLPSSY-UHFFFAOYSA-L

一般說明

氯化钯(II)是钯(II)的代表性盐,作为前体用于制备各种反应的钯催化剂,如 Heck 偶联、Suzuki 偶联、Sonagashira 偶联和 Buchwald-Hartwig 偶联。它也可用作氧化剂。

應用

用于合成含半导体金属的聚合物,其中聚吡咯骨架的构象能量最小并且几乎是平面结构。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Feng-Quan Yuan et al.
Chemical communications (Cambridge, England), 47(18), 5289-5291 (2011-04-01)
We present a PdCl(2)-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and
[(RCN)2PdCl2]-catalyzed E/Z isomerization of alkenes: a non-hydride binuclear addition-elimination pathway.
Emily H P Tan et al.
Angewandte Chemie (International ed. in English), 50(41), 9602-9606 (2011-09-23)
Maria Elisabete Machado et al.
Journal of chromatography. A, 1274, 165-172 (2013-01-10)
The separation of the organic sulfur compounds (OSC) of petroleum or its heavy fractions is a critical step and is essential for the correct characterization of these compounds, especially due to similar physical and chemical properties of polycyclic aromatic sulfur
Chun Liu et al.
Organic & biomolecular chemistry, 9(4), 1054-1060 (2010-12-15)
A simple and efficient protocol has been developed for the PdCl(2)-catalyzed ligand-free and aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with arylboronic acids in good to excellent yields in aqueous ethanol. A systematic investigation on the effect

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