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Merck
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文件

277053

Sigma-Aldrich

(S)-(+)-2-(甲氧基甲基)吡咯烷

99%

同義詞:

O-甲基-L-脯氨醇, SMP

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About This Item

經驗公式(希爾表示法):
C6H13NO
CAS號碼:
分子量::
115.17
Beilstein:
3587324
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

liquid

光學活性

[α]20/D +2.4°, c = 2 in benzene

折射率

n20/D 1.4457 (lit.)

bp

62 °C/40 mmHg (lit.)

密度

0.933 g/mL at 25 °C (lit.)

SMILES 字串

COC[C@@H]1CCCN1

InChI

1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

InChI 密鑰

CHPRFKYDQRKRRK-LURJTMIESA-N

應用

手性助剂,用于不对称合成炔丙醇 和 4-硝基环己酮, 以及用于不对称 Michael 加成反应生成烯酮。
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

113.0 °F - closed cup

閃點(°C)

45 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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