推薦產品
化驗
95%
形狀
liquid
折射率
n20/D 1.476 (lit.)
bp
70 °C/0.2 mmHg (lit.)
密度
1.089 g/mL at 25 °C (lit.)
SMILES 字串
CCCC[Sn](CCCC)(CCCC)C#C
InChI
1S/3C4H9.C2H.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H;
InChI 密鑰
YEMJHNYABQHWHL-UHFFFAOYSA-N
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應用
Ethynyltributylstannane can be used as a reactant to prepare:
- Terminal arylacetylene derivatives by Stille coupling reaction with aryl halides in the presence of palladium catalyst.[1]
- 1,4-bis(tributylstannyl)but-1-en-3-yne by dimerization using a metal complex having bulky ligand catalyst system.[2]
- Isoquinolone derivatives by reacting with benzotriazinones via denitrogenative insertion in the presence of nickel catalyst.[3]
- Enyne key intermediates in the total synthesis of (-)-acutumine and (-)-dechloroacutumine.[4]
訊號詞
Danger
危險分類
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
165.2 °F - closed cup
閃點(°C)
74 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
客戶也查看了
Total Syntheses of (-)-Acutumine and (-)-Dechloroacutumine
King SM, et al.
Angewandte Chemie (International ed. in English), 125(13), 3730-3733 (2013)
Journal of the Chemical Society. Perkin Transactions 1, 1657-1657 (1993)
Synthesis of terminal arylacetylenes by a Stille coupling reaction catalysed by a MCM-41-supported bidentate phosphine palladium (O) complex
H Wenyan, et al.
J. Chem. Res. (M), 2008(11), 615-618 (2008)
Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand
Ogoshi S, et al.
Chemical Communications (Cambridge, England), 2008(23), 2732-2733 (2004)
Synlett, 557-557 (1994)
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