263613

氯甲基膦酸二乙酯

97%

• 同義詞: Chloromethylphosphonic acid diethyl ester, NSC 67753
• 線性公式: ClCH₂PO(OC₂H₅)₂
• CAS號碼: 3167-63-3
• 分子量：: 186.57
• Beilstein: 1363361
• EC號碼: 221-632-5
• MDL號碼: MFCD00010189
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24855986

屬性

• 化驗: 97%
• 反應適用性: reaction type: C-C Bond Formation
• 折射率: n20/D 1.437 (lit.)
• bp: 109-110 °C/10 mmHg (lit.)
• 密度: 1.2 g/mL at 25 °C (lit.)
• SMILES 字串: CCOP(=O)(CCl)OCC
• InChI: 1S/C5H12ClO3P/c1-3-8-10(7,5-6)9-4-2/h3-5H2,1-2H3
• InChI 密鑰: MZBIWKMCTWJLPT-UHFFFAOYSA-N

描述

應用

Reactant involved in:

• Subsequent alkylation after nucleophilic substitution
• One-pot alkylation-boration of α-haloalkylphosphonates
• Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
• Phosphorylation leading to P-containing cyclopropanes
• Wadsworth-Emmons reactions
• Ring expansion of zircnacycles via carbenoid insertion

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 186.8 °F - closed cup
• 閃點（°C）: 86 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter