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重要文件

262099

Sigma-Aldrich

三氯氧磷(V)

99.999%

同義詞:

三氯氧化磷(V), 磷酰三氯

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About This Item

線性公式:
POCl3
CAS號碼:
分子量::
153.33
EC號碼:
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22
化驗:
99.999%
bp:
105.8 °C (lit.)
蒸汽壓力:
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
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蒸汽密度

5.3 (vs air)

品質等級

蒸汽壓力

104 mmHg ( 50 °C)
28 mmHg ( 20 °C)

化驗

99.999%

形狀

liquid

pH值

1 (20 °C)

bp

105.8 °C (lit.)

mp

1.25 °C (lit.)

密度

1.645 g/mL at 25 °C (lit.)

官能基

phosphine oxide

SMILES 字串

ClP(Cl)(Cl)=O

InChI

1S/Cl3OP/c1-5(2,3)4

InChI 密鑰

XHXFXVLFKHQFAL-UHFFFAOYSA-N

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應用

Phosphorus(V) oxychloride can be used as:
  • A dehydrating agent in organic synthesis.[1]
  • A reagent in the cyclization of substituted aryl amides by Bischler−Napieralski cyclization reaction.[2]
  • A precursor for phosphorus diffusion in the p-type silicon solar cells processing.[3]

It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.[4]

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

標靶器官

Respiratory Tract

安全危害

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

Asymmetric transfer hydrogenation of imines catalyzed by a Noyori-type Ru (II) complex-a parametric study
Pechavcek J, et al.
Tetrahedron Asymmetry, 24(4), 233-239 (2013)
Rapid one-pot radiosynthesis of [carbonyl-. sup. 11C] formamides from primary amines and [. sup. 11C] CO. sub. 2.
Luzi Federico, et al.
EJNMMI radiopharmacy and chemistry, 5(1), 377-386 (2020)
Isocyanide 2.0
Patil P, et al.
Green Chemistry, 22(20), 6902-6911 (2020)
Optimization of phosphorus emitter formation from POCl 3 diffusion for p-type silicon solar cells processing
Ghembaza H, et al.
Silicon, 10(2), 377-386 (2018)
Bo Qin et al.
Chemistry, an Asian journal, 6(12), 3298-3305 (2011-07-23)
POCl(3)-mediated one-pot macrocyclization allows the highly selective formation of five-residue macrocycles that are rigidified by internally placed intramolecular hydrogen bonds. Mechanistic investigation by using tailored competition experiments and kinetic simulation provides a comprehensive model, supporting a chain-growth mechanism underlying the

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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