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重要文件

234184

Sigma-Aldrich

苯磺酰乙酸甲酯

97%

同義詞:

苯磺酰基乙酸甲酯

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About This Item

線性公式:
C6H5SO2CH2COOCH3
CAS號碼:
分子量::
214.24
Beilstein:
2051463
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

97%

折射率

n20/D 1.535 (lit.)

bp

165 °C/0.05 mmHg (lit.)

密度

1.305 g/mL at 20 °C (lit.)

官能基

ester
sulfone

SMILES 字串

COC(=O)CS(=O)(=O)c1ccccc1

InChI

1S/C9H10O4S/c1-13-9(10)7-14(11,12)8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI 密鑰

NLEAIFBNKPYTGN-UHFFFAOYSA-N

基因資訊

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應用

Methyl phenylsulfonylacetate has been used:
  • in a key step during the synthesis of (−)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida[1]
  • in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium[2]
  • in three step synthesis of 2-(hydroxymethyl)indene[3]

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

172.4 °F - closed cup

閃點(°C)

78 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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分析證明 (COA)

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An improved synthesis of 2-(hydroxymethyl) indene.
Palandoken H, et al.
Organic Prep. and Proc. Int., 28(6), 702-704 (1996)
Methyl Carboxymethylenation of Alcohols via Dehydrative Alkylation.
YuJ, et al.
Synlett, 1995(11), 1127-1128 (1995)
Koichiro Ota et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(42), 13531-13537 (2012-09-12)
(-)-Hybridalactone (1) is a marine eicosanoid isolated from the red alga Laurencia hybrida. This natural product contains cyclopropane, cyclopentane, 13-membered macrolactone and epoxide ring systems incorporating seven stereogenic centers. Moreover, this compound has an acid-labile skipped Z,Z-diene motif. In this

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