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Merck
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文件

227722

Sigma-Aldrich

六氟磷酸银

98%

同義詞:

Silver(I) hexafluorophosphate

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About This Item

線性公式:
AgPF6
CAS號碼:
分子量::
252.83
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

solid

反應適用性

core: silver
reagent type: catalyst

mp

102 °C (dec.) (lit.)

SMILES 字串

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI 密鑰

SCQBROMTFBBDHF-UHFFFAOYSA-N

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相關類別

一般說明

六氟磷酸银可作为催化剂用于硫酰亚胺化(sulfimidation)、醛氢化转化为醇以及炔烃和羧酸的氢酰氧基化(hydroacyloxylation)

應用

(六氟锑酸银)用于制备3,3′-二氰基二苯基乙炔银配位网络,以研究配体对网络结构的作用,以便研制新型材料。(六氟锑酸银)可制备银配合物的超分子网络。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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