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重要文件

220884

Sigma-Aldrich

2-噻吩甲胺

96%

同義詞:

2-(氨甲基)噻吩

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About This Item

經驗公式(希爾表示法):
C5H7NS
CAS號碼:
分子量::
113.18
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

96%

形狀

liquid
liquid

折射率

n20/D 1.5670 (lit.)

bp

95-99 °C/28 mmHg (lit.)

密度

1.103 g/mL at 25 °C (lit.)

官能基

amine

SMILES 字串

NCc1cccs1

InChI

1S/C5H7NS/c6-4-5-2-1-3-7-5/h1-3H,4,6H2

InChI 密鑰

FKKJJPMGAWGYPN-UHFFFAOYSA-N

一般說明

2-噻吩甲胺是一种聚(3-己基噻吩)/CdSe杂化太阳能电池的潜在配体替代品[1]

應用

2-噻吩甲胺可用于制备:
  • 萘-噻吩杂化分子(Z)-1-((噻吩-2-基甲基氨基)亚甲基)萘-2-(1H)-酮[2]
  • 荧光Pd2+ 传感器,N丁基-4-(p-甲氧)-苯基乙炔基-5-噻吩甲氨基-1,8-萘二甲酰亚胺[3]
作为反应物用于合成:
  • 三唑连接的噻吩共轭物,用作金属硫蛋白的金属解毒和氧化应激研究中的仿生模型
  • 血清素 5-HT1A受体拮抗剂,其对缺血性细胞损伤具有神经保护作用
  • 含咪唑和胡椒基的噻二唑和嘧啶,用作诱导型氧化物合酶二聚化抑制剂
  • 光电分段聚氨酯

作为以下反应的反应物:
  • 有机催化酮不对称还原胺化的研究
  • 胺与亚胺的无金属好氧氧化偶联反应

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

165.2 °F - closed cup

閃點(°C)

74 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Debasis Karak et al.
Dalton transactions (Cambridge, England : 2003), 42(19), 6708-6715 (2013-04-10)
A naphthalene-thiophene hybrid molecule (Z)-1-((thiophen-2-ylmethylamino)methylene)naphthalen-2(1H)-one () was prepared by condensation of 2-thiophenemethylamine and 2-hydroxy-1-naphthaldehyde. According to FTIR, (1)H NMR spectrometry and single crystal X-ray analysis, exists in the cis-keto-amine tautomeric form. behaves like a molecular AND type binary logic gate
Liping Duan et al.
Chemical communications (Cambridge, England), (47)(47), 6339-6341 (2008-12-03)
A new fluorescent Pd2+ sensor , N-butyl-4-(p-methyloxy)-phenylethynyl-5-thiophenemethylamino-1,8-naphthalimide, was designed and synthesized. It showed highly selective on-off fluorescence changes for Pd2+ among the representative transition and heavy metallic cations, and its fluorescence was efficiently quenched by 5 equivalents of Pd2+ in
Jun Yan Lek et al.
ACS applied materials & interfaces, 3(2), 287-292 (2011-01-26)
For hybrid solar cells, interfacial chemistry is one of the most critical factors for good device performance. We have demonstrated that the size of the surface ligands and the dispersion of nanoparticles in the solvent and in the polymer are
Adesola Abimbola Adeleke et al.
Journal of inorganic biochemistry, 214, 111266-111266 (2020-11-10)
Synthesis and spectroscopic characterization of five ligands ((E)-2-((pyridin-2-ylmethylene)amino)phenol L1, 2-(pyridin-2-yl)benzo[d]thiazole L2, (E)-N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine L3, (E)-1-(pyridin-2-yl)-N-(p-tolyl)methanimine L4 and (E)-1-(pyridin-2-yl)-N-(thiophen-2-ylmethyl)methanimine L5 along with fifteen silver(I) complexes of L1 - L5, with a general formula [AgL2]+X- (L = Schiff base and X = NO3-, ClO4- or CF3SO3-) is

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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