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Merck
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209686

Sigma-Aldrich

powder, 99.9% trace metals basis

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About This Item

經驗公式(希爾表示法):
Ir
CAS號碼:
分子量::
192.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12141720
PubChem物質ID:
NACRES:
NA.23

化驗

99.9% trace metals basis

形狀

powder

電阻係數

4.71 μΩ-cm

bp

4130 °C (lit.)

mp

2450 °C (lit.)

密度

22.65 g/cm3 (lit.)

SMILES 字串

[Ir]

InChI

1S/Ir

InChI 密鑰

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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一般說明

Iridium is a rare and dense transition metal that belongs to the platinum group of metals and is known for its remarkable physical and chemical properties. Iridium is used in high-temperature applications such as crucibles for crystal growth and in devices that operate under extreme conditions due to its high melting point and stability at elevated temperatures. It is also used in electrical contacts and electrodes because of its excellent corrosion resistance and electrical conductivity. In addition, iridium is used as a catalyst in various organic reactions including hydrogenation, water splitting, C-C coupling, and olefin metathesis.

應用

  • 用于酸性介质中高效水氧化的铱基双钙钛矿:该研究强调了基于铱的双钙钛矿的开发,该物质可以在降低铱含量的同时保持水氧化的高活性和稳定性,对于材料科学中与能源相关的应用具有重要意义(Diaz-Morales et al., 2016)。
  • 氧化铱析氧反应机理的研究进展:本文分析了氧化铱析氧反应(OER)机制,这对于改善工业应用中的催化过程至关重要(Naito et al., 2021)。
  • 氧化铱的制备及应用:回顾:一篇全面的综述,讨论铱氧化物的各种制造方法及其应用,特别是与药物发现和材料科学相关的传感器和催化剂方面(Chen et al., 2020)。

象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Flam. Sol. 1

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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Rui Cao et al.
Journal of medicinal chemistry, 56(9), 3636-3644 (2013-04-19)
The cellular behavior and toxicity effect of organometallic complexes depend largely on their peripheral ligands. In this study, we have synthesized a series of novel luminescent cationic iridium(III) complexes by tuning the ancillary N(∧)N ligand based on a structure [Ir(ppy)2(N(∧)N)](+)
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
Matthew R Kelley et al.
Inorganic chemistry, 52(5), 2564-2580 (2013-02-21)
A series of seven [Ir{ArNC(NR2)NAr}(cod)] complexes (1a-1g; where R = Me or Et; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 2,6-Me2C6H3, or 2,6-(i)Pr2C6H3; and cod = 1,5-cyclooctadiene) were synthesized by two different methods from the neutral guanidines, ArN═C(NR2)NHAr, using either MeLi and
M Y Zhang et al.
Optics express, 21 Suppl 1, A173-A178 (2013-02-15)
We have investigated the transport characteristics of red phosphorescent dye bis(1-(phenyl)isoquinoline) iridium (III) acetylanetonate (Ir(piq)₂acac) doped 4,4',4"-tri(N-carbazolyl)triphenylamine (TCTA), and found that the increasing doping ratio was facilitated to improve the ability of hole transporting. A high color rendering index (CRI)
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols

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