推薦產品
形狀
liquid
品質等級
濃度
2.0 M in toluene
密度
0.81 g/mL at 25 °C
SMILES 字串
C[Al](C)C
InChI
1S/3CH3.Al/h3*1H3;
InChI 密鑰
JLTRXTDYQLMHGR-UHFFFAOYSA-N
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應用
三甲基铝溶液可用作合成以下物质的试剂:
- 通过不饱和糖苷的立体选择性重排生成多羟基化环己烷
- 用于烯烃聚合的部分水解三甲基铝(PHT)催化剂
- 采用镍-1,3-二环己基咪唑2-亚基催化体系通过苯甲醚衍生物的甲基化作用生成甲苯
用于最近报道的基于Oppenauer 反应的Al催化氧化,得到了高产量的醛和酮。 作为联萘酚的 (1:1) 络合物,以Novozym 435催化仲醇的动态动力学拆分。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
39.2 °F - closed cup
閃點(°C)
4 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Journal of Applied Polymer Science, 80(3), 454-466 (2001)
Nickel-catalyzed cross-coupling of anisole derivatives with trimethylaluminum through the cleavage of carbon-oxygen bonds
Morioka T, et al.
Chemistry Letters (Jpn), 44(12), 1729-1731 (2015)
Christopher R Graves et al.
Journal of the American Chemical Society, 128(39), 12596-12597 (2006-09-28)
A highly active and selective Al-based catalytic Oppenauer (O) oxidation is reported. Quantitative and selective oxidations of a variety of benzylic, propargylic, allylic, and aliphatic primary and secondary alcohols were achieved using nitrobenzaldehyde derivatives as the oxidant and simple aluminum
Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes
Jia C, et al.
Tetrahedron Asymmetry, 15(4), 699-703 (2004)
Lipase/aluminum-catalyzed dynamic kinetic resolution of secondary alcohols.
Albrecht Berkessel et al.
Angewandte Chemie (International ed. in English), 45(39), 6567-6570 (2006-09-05)
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