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Merck
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重要文件

160938

Sigma-Aldrich

Resolve-Al EuFOD

99%

同義詞:

Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕

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About This Item

線性公式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
CAS號碼:
分子量::
1037.49
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
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化驗

99%

形狀

solid

反應適用性

core: erbium
reagent type: catalyst

mp

203-207 °C

SMILES 字串

CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

InChI 密鑰

PTQJQBFRLLGICD-VNGPFPIXSA-K

尋找類似的產品? 前往 產品比較指南

一般說明

在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。

應用

当与 Resolve-Al AgFOD 结合使用时,可为芳香族化合物、[1]铵盐[2]以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。[3]

法律資訊

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析證明 (COA)

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A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
Michiya Fujiki et al.
Frontiers in chemistry, 8, 685-685 (2020-09-10)
We report emerging circularly polarized luminescence (CPL) at 4f-4f transitions when lanthanide (EuIII and TbIII) tris(β-diketonate) embedded to cellulose triacetate (CTA), cellulose acetate butyrate (CABu), D-/L-glucose pentamethyl esters ( D-/ L-Glu), and D-/L-arabinose tetramethyl esters ( D-/ L-Ara) are in
J P Caldwell et al.
Journal of forensic sciences, 46(6), 1332-1341 (2001-11-21)
The utilization of the lanthanide shift reagent tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) europium (III) [Eu(fod)3] as a simple one-step reagent for the luminescent visualization of latent fingerprints has been investigated. UV excitation of Eu(fod)3-treated prints, achieved by using a hand-held UV lamp or

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