15145

(-)-双[(S)-1-苯基乙基]胺 盐酸盐

≥98.0% (AT)

• 同義詞: (-)-双[(S)-α-甲苄基]胺 盐酸盐
• 經驗公式（希爾表示法）: C₁₆H₁₉N · HCl
• CAS號碼: 40648-92-8
• 分子量：: 261.79
• Beilstein: 4723969
• MDL號碼: MFCD00216671
• 分類程式碼代碼: 12352116
• PubChem物質ID: 57647325
• NACRES: NA.22

屬性

• 化驗: ≥98.0% (AT)
• 形狀: solid
• 光學活性: [α]20/D −73±2°, c = 3% in ethanol
• mp: ~260 °C
• SMILES 字串: Cl.C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
• InChI: 1S/C16H19N.ClH/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16;/h3-14,17H,1-2H3;1H/t13-,14-;/m0./s1
• InChI 密鑰: ZBQCLJZOKDRAOW-IODNYQNNSA-N

描述

應用

(−)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:

• To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.[1]
• As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.[2]
• As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using ³¹P NMR.[3]

其他說明

对应的手性氨基化锂可作为碱，用于酮的对映选择性脱质子化反应。[4][5][6][7]

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves