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重要文件

150452

Sigma-Aldrich

6-溴己酸

97%

同義詞:

6-溴代己酸

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About This Item

線性公式:
BrCH2(CH2)4COOH
CAS號碼:
分子量::
195.05
Beilstein:
1749740
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

97%

形狀

solid

bp

165-170 °C/20 mmHg (lit.)

mp

32-34 °C (lit.)

官能基

bromo
carboxylic acid

SMILES 字串

OC(=O)CCCCCBr

InChI

1S/C6H11BrO2/c7-5-3-1-2-4-6(8)9/h1-5H2,(H,8,9)

InChI 密鑰

NVRVNSHHLPQGCU-UHFFFAOYSA-N

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應用

6-溴己酸被用于在使用甲苯磺酰异氰酸酯(189278)[1]处理时制备N-酰基磺酰胺,以及从烷基碘和金属锶制备烷基酮。[2]它还用于合成阴离子丝裂霉素C-葡聚糖偶联物(MMC-D)[3]、2-锂-1,3-二噻烷[4]和二芳基硫醚[5]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

203.0 °F - closed cup

閃點(°C)

95 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

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S S Pochapsky et al.
Bioconjugate chemistry, 1(4), 231-244 (1990-07-01)
A versatile method for the synthesis of trifluoro fatty acids, potential metabolically blocked myocardial imaging agents, has been developed. Two trifluorohexadecanoic (palmitic) acids have been prepared [6,6,16-trifluorohexadecanoic acid (I) and 7,7,16-trifluorohexadecanoic acid (II)], each of which bears two of the
Vinzenz Bachler
Journal of computational chemistry, 28(12), 2013-2019 (2007-04-05)
Localized bonding schemes and their weights have been obtained for the pi-electron system of nitrone by expanding complete active space self-consistent field wave functions into a set of Slater determinants composed of orthogonal natural atomic orbitals (NAOs) of Weinhold and
Tetrahedron Letters, 48, 787-787 (2007)
S Matsumoto et al.
Cancer research, 46(9), 4463-4468 (1986-09-01)
Cellular interaction and in vitro antitumor activity of a polymeric prodrug of mitomycin C (MMC), mitomycin C-dextran conjugate (MMC-D), were studied in relation to its physicochemical characteristics. MMC-D with cationic and anionic charges were examined. The cationic MMC-D was synthesized
D Poirier et al.
Journal of medicinal chemistry, 37(8), 1115-1125 (1994-04-15)
The reaction of 1,2-diarylethanol and mercapto side chain catalyzed by ZnI2 was used as a key step in the short (three to five steps) and efficient synthesis of 17 diaryl thioether derivatives. Several of these compounds contain a methyl butyl

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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