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130850

Sigma-Aldrich

3-丁炔-1-醇

97%

同義詞:

3-Butynol

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About This Item

線性公式:
HC≡CCH2CH2OH
CAS號碼:
927-74-2
分子量：:
70.09
Beilstein:
773710
EC號碼:
213-161-9
MDL號碼:
MFCD00002955
分類程式碼代碼:
12352100
eCl@ss:
39020335
PubChem物質ID:
24847980
NACRES:
NA.22
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品質等級

200

化驗

97%

形狀

liquid

折射率

n20/D 1.441 (lit.)

bp

128.9 °C (lit.)

mp

−63.6 °C (lit.)

密度

0.926 g/mL at 25 °C (lit.)

官能基

hydroxyl

SMILES 字串

OCCC#C

InChI

1S/C4H6O/c1-2-3-4-5/h1,5H,3-4H2

InChI 密鑰

OTJZCIYGRUNXTP-UHFFFAOYSA-N

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相關類別

一般說明

3-丁炔-1-醇的燃烧和汽化焓用静态燃烧量热法和相关气相色谱法测量 [1]。

應用

3-丁炔-1-醇用于制备马氏加成物 [2]。
合成元用于制备含氧杂环[3] 和受保护的s-羟基-L-异亮氨酸酯
在钯催化偶合 β-tetrionic酸溴化物的研究中，使用炔基底物，可使生成炔基取代呋喃酮的产量很高。 [4]

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

96.8 °F - closed cup

閃點（°C）

36 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析證明 (COA)

Lot/Batch Number
MKCX1174
MKCV7254
MKCT0030
MKCR2865
MKBB6950

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存取文件庫

Kopf, Henning; Pietraszuk. et al.
Organometallics, 25(10), 2533-2546 (2006)
Tetrahedron Letters, 48, 105-105 (2007)
Ederley Vélez et al.
The journal of physical chemistry. A, 109(34), 7832-7838 (2006-07-13)
The enthalpies of combustion and vaporization of 3-buten-1-ol and 3-butyn-1-ol have been measured by static bomb combustion calorimetry and correlation gas chromatography techniques, respectively, and the gas-phase enthalpies of formation, Delta(f)H degrees (m)(g), have been determined, the values being -147.3
Deniz Dogruer et al.
Bioorganic & medicinal chemistry letters, 14(2), 523-526 (2003-12-31)
The binding of a series pyridylbutynylamines 6 was examined at alpha4beta2 nACh receptors. Structural modifications, comparing 6 with pyridyl ethers 2, did not consistently result in parallel effects on receptor affinity, suggesting possible differences in their modes of binding. Furthermore
Sumod A Pullarkat et al.
Inorganic chemistry, 45(18), 7455-7463 (2006-08-29)
Alcohol functionalized diphosphine ligands with chirality residing on the carbon backbone were prepared using a novel two-stage asymmetric synthetic methodology from the corresponding terminal alkynols. Under mild conditions, the alkynols, 3-butyn-1-ol and 2-propyn-1-ol, were subjected to direct hydrophosphination to give
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文章

Functionalized Alkynes

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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