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Merck
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重要文件

118559

Sigma-Aldrich

1,5-己二烯-3-醇

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About This Item

線性公式:
H2C=CHCH2CH(OH)CH=CH2
CAS號碼:
分子量::
98.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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折射率

n20/D 1.448 (lit.)

密度

0.878 g/mL at 25 °C (lit.)

官能基

allyl
hydroxyl

SMILES 字串

OC(CC=C)C=C

InChI

1S/C6H10O/c1-3-5-6(7)4-2/h3-4,6-7H,1-2,5H2

InChI 密鑰

SZYLTIUVWARXOO-UHFFFAOYSA-N

一般說明

1,5-Hexadien-3-ol is the starting reagent for the enantioselective synthesis of (+)-rogioloxepane A[1]. It undergoes Sharpless kinetic resolution and ring-closing metathesis to yield nine membered oxocene[2].

應用

1,5-Hexadien-3-ol was used in the synthesis of (+)-obtusenyne[2].

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

84.2 °F - closed cup

閃點(°C)

29 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Michael T Crimmins et al.
Journal of the American Chemical Society, 125(25), 7592-7595 (2003-06-19)
A total synthesis of the laurencia metabolite (+)-obtusenyne has been completed. The key steps include a Sharpless kinetic resolution and an asymmetric glycolate alkylation to establish the stereogenic centers adjacent to the ether linkage and a ring-closing metathesis reaction to
Yan-Lun Ju et al.
Plant physiology and biochemistry : PPB, 130, 501-510 (2018-08-11)
Grapes are one of the most important fruits because of their economic and nutritional benefits, and grapevines are widely cultivated in arid and semi-arid areas. Therefore, it is critical to study the mechanism by which grapevines respond to water stress.
Induction of rejection of successful allografts of rat islets by donor peritoneal exudate cells.
P E Lacy et al.
Transplantation, 28(5), 415-420 (1979-11-01)

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