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Merck
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重要文件

111627

Sigma-Aldrich

2-甲基-1-己烯

96%

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About This Item

線性公式:
CH3(CH2)3C(CH3)=CH2
CAS號碼:
分子量::
98.19
Beilstein:
1732738
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度

1 (vs air)

化驗

96%

折射率

n20/D 1.403 (lit.)

bp

92 °C (lit.)

密度

0.697 g/mL at 25 °C (lit.)

SMILES 字串

CCCCC(C)=C

InChI

1S/C7H14/c1-4-5-6-7(2)3/h2,4-6H2,1,3H3

InChI 密鑰

IRUDSQHLKGNCGF-UHFFFAOYSA-N

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一般說明

2-Methyl-1-hexene is a less reactive olefin that is hydroformylated in the presence of phosphite-modified rhodium catalysts[1]. The epoxidation of 2-methyl-1-hexene is catalyzed by human and rat P450 enzymes[2].

象形圖

FlameHealth hazard

訊號詞

Danger

危險聲明

危險分類

Asp. Tox. 1 - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

17.6 °F - closed cup

閃點(°C)

-8 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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C Chiappe et al.
Chemical research in toxicology, 11(12), 1487-1493 (1998-12-22)
The epoxidation of 1-hexene (1a) and 2-methyl-1-hexene (1b), two hydrocarbons present in the ambient air as pollutants, is catalyzed by some human and rat P450 enzymes. The enantioselectivities of these processes, when the reactions were carried out using rat and
Hydroformylation of less reactive olefins with modified rhodium catalysts.
Van Leeuwen PWNM and Roobeek CF.
Journal of Organometallic Chemistry, 258(3), 343-350 (1983)
Hiroshi Toda et al.
Applied and environmental microbiology, 81(6), 1919-1925 (2015-01-04)
We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the organic solvent-tolerant microorganism Kocuria rhizophila DC2201, and the bioconversion reaction was performed in an

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