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Merck
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文件

109258

Sigma-Aldrich

丙酸甲酯

99%

同義詞:

Methyl propanoate, Propionic acid methyl ester

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About This Item

線性公式:
CH3CH2COOCH3
CAS號碼:
分子量::
88.11
Beilstein:
1737628
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
eCl@ss:
39022202
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3 (vs air)

品質等級

蒸汽壓力

40 mmHg ( 11 °C)
85.3 mmHg ( 25 °C)

化驗

99%

自燃溫度

876 °F

expl. lim.

13 %

折射率

n20/D 1.376 (lit.)

bp

79 °C (lit.)

mp

−88 °C (lit.)

溶解度

H2O: soluble 16 parts
alcohol: miscible
diethyl ether: miscible

密度

0.915 g/mL at 25 °C (lit.)

SMILES 字串

CCC(=O)OC

InChI

1S/C4H8O2/c1-3-4(5)6-2/h3H2,1-2H3

InChI 密鑰

RJUFJBKOKNCXHH-UHFFFAOYSA-N

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一般說明

丙酸甲酯是一种用于猪胰脂肪酶(PPL)催化各种二醇的酯交换反应的有效溶剂。它通常用于有机合成。它可与甲醛通过气相醛醇缩合反应形成甲基丙烯酸甲酯

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

28.4 °F - closed cup

閃點(°C)

-2 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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PPL-catalyzed resolution of 1, 2-and 1, 3-diols in methyl propionate as solvent. An application of the tandem use of enzymes.
Janssen AJM and Zwanenburg B.
Tetrahedron, 47(35), 7409-7416 (1991)
Formation of methyl methacrylate by condensation of methyl propionate with formaldehyde over silica-supported cesium hydroxide catalysts.
Ai M.
Applied Catalysis A: General, 288(1), 211-215 (2005)
Jonathan Slaughter et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(1), 167-175 (2016-10-30)
In investigating and seeking to mimic the reactivity of trimethylaluminium (TMA) with synthetic, ester-based lubricating oils, the reaction of methyl propionate 1 was explored with 1, 2 and 3 equivalents of the organoaluminium reagent. Spectroscopic analysis points to the formation of
Sang-Ryong Lee et al.
The Science of the total environment, 610-611, 992-996 (2017-08-26)
This report proposes a new approach to evaluate the odour nuisance of cattle manure samples from three different cattle breeds (i.e., native cattle, beef cattle, and milk cow) by means of quantification and speciation of volatile fatty acids (VFAs). To
Ileana M Pazos et al.
Angewandte Chemie (International ed. in English), 53(24), 6080-6084 (2014-05-03)
The ability to quantify the local electrostatic environment of proteins and protein/peptide assemblies is key to gaining a microscopic understanding of many biological interactions and processes. Herein, we show that the ester carbonyl stretching vibration of two non-natural amino acids

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