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等級
produced by Wacker Chemie AG, Burghausen, Germany
化驗
≥96% (GC)
製造商／商標名
Wacker Chemie AG
折射率
n20/D 1.441 (lit.)
bp
107 °C/14 mmHg (lit.)
密度
1.19 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(=O)C(Cl)C(C)=O
InChI
1S/C6H9ClO3/c1-3-10-6(9)5(7)4(2)8/h5H,3H2,1-2H3
InChI 密鑰
RDULEYWUGKOCMR-UHFFFAOYSA-N
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應用
Ethyl 2-chloroacetoacetate was used to study reductive dechlorination of β-keto ester ethyl 2-chloroacetoacetate by Saccharomyces cerevisiae[1].
生化／生理作用
Ethyl 2-chloroacetoacetate reacts with thiosemicarbazones to form heterocyclic substituted thiophene derivatives having non-steroidal anti-inflammatory activity[2].
其他說明
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訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
179.6 °F
閃點（°C）
82 °C
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and antiinflammatory activity of novel 2, 5-disubstituted thiophene derivatives.
Badr SMI.
Turkish Journal of Chemistry, 35(1), 131-143 (2011)
P M Flanagan et al.
Journal of molecular biology, 206(2), 295-304 (1989-03-20)
The Tn3-encoded resolvase protein promotes a site-specific recombination reaction between two directly repeated copies of the recombination site res. Several inhibitors that block this event in vitro have been isolated. In this study four of these inhibitors were tested on
Gerhard Jörg et al.
Chembiochem : a European journal of chemical biology, 5(1), 87-92 (2003-12-26)
Saccharomyces cerevisiae reduces the beta-keto ester ethyl 2-chloroacetoacetate to the respective chiral cis- and trans-beta-hydroxy esters. In the course of chiral reduction, competing dehalogenation of the xenobiotic substrate to ethyl acetoacetate occurs, in a reaction mediated by cytosolic glutathione (GSH).
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