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Merck

239267

Sigma-Aldrich

硝酸钴(II) 六水合物

ACS reagent, ≥98%

别名:

硝酸亚钴, 硝酸亚钴 六水合物, 硝酸,钴(II)盐

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5 G
$119.00
100 G
$178.00
500 G
$703.00

About This Item

线性分子式:
Co(NO3)2 · 6H2O
CAS号:
分子量:
291.03
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21

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等级

ACS reagent

质量水平

方案

≥98%
98.0-102.0%

表单

chips
powder, crystals or chunks
solid

反应适用性

reagent type: catalyst
core: cobalt

杂质

≤0.01% insolubles

pH值(酸碱度)

4 (20 °C, 100 g/L)

mp

55 °C (lit.)

痕量阴离子

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.005%

痕量阳离子

Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Mg: ≤0.005%
NH4+: ≤0.2%
Na: ≤0.05%
Ni: ≤0.15%
Pb: ≤0.002%
Zn: ≤0.01%

SMILES字符串

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

InChI key

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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一般描述

硝酸钴六水合物为红褐色晶体结构,溶于水和有机溶剂。常用于制备钴催化剂、色素、化学品和维生素B12。在电子行业中还用作高纯度钴源。 [1] [2]

应用

硝酸钴(II)六水合物可作为催化剂用于合成:
  • 5-羧酰苯胺-二氢嘧啶酮衍生物,通过乙酰乙酰苯胺、醛和脲/硫脲的缩合来合成。
  • 通过使用 -亚硝酸丁酯作为硝基源对吲哚进行硝化得到硝基吲哚。
  • 在膦配体存在下用醇从2-氨基苯腈制备喹唑啉酮。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

靶器官

Lungs

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Preparation of a cobalt metal-organic framework (Co-MOF) and its application as a polypropylene flame retardant by compounding with melamine polyphosphate
Ya Xu, et al.
Polymer Testing, 116, 107765-107765 (2022)
Chlorinated drinking water; chlorination byproducts; some other halogenated compounds; cobalt and cobalt compounds
International Agency for Research on Cancer and others
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans / World Health Organization, International Agency for Research on Cancer, 52, 363-472 (1991)
Some Phosphine Oxide and Arsine Oxide Complexes of Cobalt (II) Nitrate.
Cotton FA, et al.
Inorganic Chemistry, 2(6), 1162-1165 (1963)
Thermal decomposition of cobalt nitrato compounds: Preparation of anhydrous cobalt (II) nitrate and its characterisation by Infrared and Raman spectra.
Ehrhardt C, et al.
Thermochimica Acta, 432(1), 36-40 (2005)
Horacio López-Sandoval et al.
Journal of inorganic biochemistry, 102(5-6), 1267-1276 (2008-02-29)
In this work we present the synthesis, structural and spectroscopic characterisation of a series of cobalt(II) and zinc(II) coordination compounds with benzimidazole (bz) and its 2-benzimidazole derivatives: 2-aminobenzimidazole (2ab), albendazole (abz) and tris(2-benzimidazolylmethyl)amine (ntb). The compounds were evaluated for their

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. 239267와 관련하여 입자크기를 알 수 있을까요? 저희가 원하는 사이즈는 <10μm 이하의 파우더를 구입하고 싶습니다 해당되는 스펙의 파우더가 있다면 알려주시기 바랍니다

    1 answer
    1. Particle size testing is not performed on this product and there are no options for cobalt(II) nitrate hexahydrate with particle size testing. Please consider grinding to the appropriate particle size.

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