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78780

Sigma-Aldrich

异硫氰酸苯酯

for HPLC derivatization, the detection of alcohols and amines, ≥99.0%

别名:

PITC

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25 ML
$78.40
100 ML
$281.00
500 ML
$910.00

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25 ML
$78.40
100 ML
$281.00
500 ML
$910.00

About This Item

线性分子式:
C6H5NCS
CAS号:
103-72-0
分子量:
135.19
Beilstein:
471392
EC號碼:
203-138-1
MDL號碼:
MFCD00004798
分類程式碼代碼:
12352100
PubChem物質ID:
57652756
NACRES:
NA.21

$78.40

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品質等級

200

化驗

≥99.0%

形狀

liquid

品質

for HPLC derivatization, the detection of alcohols and amines

折射率

n20/D 1.649
n20/D 1.6515 (lit.)

bp

218 °C (lit.)

mp

−21 °C (lit.)

溶解度

water: insoluble

密度

1.13 g/mL at 20 °C
1.132 g/mL at 20 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

S=C=Nc1ccccc1

InChI

1S/C7H5NS/c9-6-8-7-4-2-1-3-5-7/h1-5H

InChI 密鑰

QKFJKGMPGYROCL-UHFFFAOYSA-N

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相关类别

一般說明

异硫氰酸苯酯是芳香族异硫氰酸酯。 它参与醇的脱水反应。[1]它被广泛用于合成各种生物学上重要的杂环化合物。[2]

應用

异硫氰酸苯酯可用作衍生化试剂，用于体液中各种苯丙胺衍生物的高效液相色谱（HPLC）分析。[3]
用于伯胺和仲胺的衍生化试剂。用于通过 Edman 降解法进行多肽测序以及通过 HPLC 进行氨基酸分析。

注意

在氩气下存放

推薦產品

发现用于 HPLC 或LC-MS 分析的理想LiChropur 试剂

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

190.4 °F - closed cup

閃點（°C）

88 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCK3507
BCCG8125
BCCD5138
BCBL8662V
BCBZ7223

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Amin Zolali et al.
Combinatorial chemistry & high throughput screening, 17(7), 610-613 (2014-03-19)
An efficient, one-pot and three-component synthesis of biologically important heterocyclic compounds is described from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride at room temperature without the need to use any catalyst.
One-pot dehydrations using phenyl isothiocyanate.
Majetich G, et al.
Tetrahedron Letters, 56(23), 3326-3329 (2015)
Determination of phenylisothiocyanate derivatives of amphetamine and its analogues in biological fluids by HPLC-APCI-MS or DAD.
Bogusz MJ, et al.
Journal of Analytical Toxicology, 21(1), 59-69 (1997)
R Gheshlaghi et al.
Analytical biochemistry, 383(1), 93-102 (2008-08-30)
Modified resolution and overall separation factors used to quantify the separation of complex chromatography systems are described. These factors were proven to be applicable to the optimization of amino acid resolution in reverse-phase (RP) HPLC chromatograms. To optimize precolumn derivatization
Misako Aito-Inoue et al.
Journal of agricultural and food chemistry, 54(15), 5261-5266 (2006-07-20)
For the isolation and detection of food-derived peptides in blood, an approach based on the derivatization of peptides with phenyl isothiocyanate (PITC) was developed. This approach allows hydrophilic peptides to be resolved and specifically detected by reversed-phase (RP) HPLC. For
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