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Merck

72910

Sigma-Aldrich

4-硝基苯甲酸

purum, ≥98.0% (HPLC)

别名:

p-Nitrobenzoic acid

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50 G
$70.90
250 G
$101.00
1 KG
$143.00

About This Item

线性分子式:
O2NC6H4CO2H
CAS号:
分子量:
167.12
Beilstein:
973593
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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等级

purum

质量水平

方案

≥98.0% (HPLC)

表单

crystals

mp

237-240 °C (lit.)
239-242 °C

官能团

carboxylic acid
nitro

SMILES字符串

OC(=O)c1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H5NO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4H,(H,9,10)

InChI key

OTLNPYWUJOZPPA-UHFFFAOYSA-N

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应用

4-Nitrobenzoic acid can be used:
  • As a co-catalyst with thioxotetrahydropyrimidinone for the α-alkylation of ketones.[1]
  • For the synthesis of mononuclear zinc carboxylate complexes by reacting with zinc sulfate heptahydrate and NaOH.[2]
  • As an additive in the room temperature catalytic Wittig reaction.[3]

象形图

Health hazardExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 2 - Repr. 2 - Skin Irrit. 2

储存分类代码

13 - Non Combustible Solids

WGK

WGK 2

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Enantioselective Organocatalytic ?-Alkylation of Ketones by SN1-Type Reaction of Alcohols.
Trifonidou M and Kokotos CG
European Journal of Organic Chemistry, 2012(8), 1563-1568 (2012)
Synthesis and characterization of zinc benzoate complexes through combined solid and solution phase reactions.
Karmakar A and Baruah JB
Polyhedron, 27(17), 3409-3416 (2008)
Breaking the ring through a room temperature catalytic Wittig reaction.
O'Brien CJ, et al.
Chemistry?A European Journal , 19(19), 5854-5858 (2013)
Zhifen Lin et al.
Chemical research in toxicology, 16(10), 1365-1371 (2003-10-21)
Quantitative structure-activity relationship (QSAR) approaches are proposed in this study to predict the joint effects of mixture toxicity. The initial investigation studies the joint effects between cyanogenic toxicants and aldehydes to Photobacterium phosphoreum. Joint effects are found to result from
Li Lin et al.
Chemosphere, 78(1), 66-71 (2009-10-23)
This paper describes the microwave (MW) treatment of soil contaminated by chloramphenicol (CAP), using granular activated carbon (GAC) as MW absorbent. It was found that the addition of GAC effectively increased the temperature of soil. Large MW power and GAC

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