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Merck

271454

Sigma-Aldrich

二丁醚

anhydrous, 99.3%

别名:

丁醚

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100 ML
$108.00
1 L
$208.00

$108.00


预计发货时间2025年6月18日详情


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100 ML
$108.00
1 L
$208.00

About This Item

线性分子式:
[CH3(CH2)3]2O
CAS号:
分子量:
130.23
Beilstein:
1732752
EC 号:
MDL编号:
UNSPSC代码:
12352112
PubChem化学物质编号:
NACRES:
NA.21

$108.00


预计发货时间2025年6月18日详情


获取大包装报价

等级

anhydrous

质量水平

蒸汽密度

4.48 (vs air)

蒸汽压

4.8 mmHg ( 20 °C)

方案

99.3%

表单

liquid

自燃温度

365 °F

expl. lim.

8.5 %

杂质

<0.005% water

蒸发残留物

<0.0005%

折射率

n20/D 1.399 (lit.)

pH值(酸碱度)

5.2

沸点

142-143 °C (lit.)

mp

−98 °C (lit.)

溶解性

H2O: 0.113 g/L at 20 °C

密度

0.764 g/mL at 25 °C (lit.)

SMILES字符串

CCCCOCCCC

InChI

1S/C8H18O/c1-3-5-7-9-8-6-4-2/h3-8H2,1-2H3

InChI key

DURPTKYDGMDSBL-UHFFFAOYSA-N

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一般描述

二丁基醚因其在水中不混溶、十六烷编号高、能量含量高等特点,被认为是柴油机的代用燃料。[1]
二丁基醚常用作各种反应的溶剂。它与多种有机溶剂形成共沸混合物,用顶空气相色谱法研究了二元混合物的汽液平衡。[2]

应用

二丁基醚可作为 1-甲氧基-1,4-环己二烯与五羰基铁反应合成三羰基 [(1,2,3,4-η)-1-和 2-甲氧基-1,3-环己二烯] 铁的溶剂。[3]

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象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

82.4 °F - closed cup

闪点(°C)

28 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A chemical kinetic study of the oxidation of dibutyl-ether in a jet-stirred reactor.
Thion S, et al.
Combustion and Flame, 185, 4-15 (2017)
Solubility of anthracene in binary alcohol+ dibutyl ether solvent mixtures.
Powell JR and Acree Jr.
Journal of Chemical and Engineering Data, 40(4), 914-916 (1995)
Seon-Joo Choi et al.
ACS applied materials & interfaces, 10(37), 31404-31412 (2018-08-28)
All-solid-state lithium batteries (ASSLBs) based on sulfide solid electrolytes (SEs) have received great attention because of the high ionic conductivity of the SEs, intrinsic thermal safety, and higher energy density achievable with a Li metal anode. However, studies on practical
Tricarbonyl [(2, 3, 4, 5-?)-2, 4-Cyclohexadien-1-One] Iron and Tricarbonyl [(1, 2, 3, 4, 5-?)-2-Methoxy-2, 4-Cyclohexadien-1-yl] Iron (1+) Hexafluorophosphate (1-) from Anisole.
Birch AJ &amp; Chamberlain KB
Organic Syntheses, 57, 107-107 (1977)
Yangang Ren et al.
The Science of the total environment, 749, 141406-141406 (2020-08-21)
Phytohormones emitted into the atmosphere perform many functions relating to the defence, pollination and competitiveness of plants. To be effective, their atmospheric lifetimes must be sufficient that these signals can be delivered to their numerous recipients. We investigate the atmospheric

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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