推荐产品
蒸汽密度
5.1 (vs air)
质量水平
蒸汽压
<0.01 mmHg ( 20 °C)
产品线
ReagentPlus®
方案
99%
表单
flakes
自燃温度
1058 °F
expl. lim.
10.4 %
沸点
284 °C (lit.)
mp
131-134 °C (lit.)
官能团
anhydride
ester
SMILES字符串
O=C1OC(=O)c2ccccc12
InChI
1S/C8H4O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h1-4H
InChI key
LGRFSURHDFAFJT-UHFFFAOYSA-N
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一般描述
Phthalic anhydride is an industrially important chemical. It can be prepared from o-xylene or naphthalene.[1] It is widely used for the industrial preparation of plasticizers for PVC (polyvinyl chloride).[2]
Phthalic anhydride can be synthesized via oxidation of o-xylene, in the presence of V2O5/TiO2 monolithic catalyst supported by aluminium honeycomb.[3]
Phthalic anhydride can be synthesized via oxidation of o-xylene, in the presence of V2O5/TiO2 monolithic catalyst supported by aluminium honeycomb.[3]
应用
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
305.6 °F - DIN 51758
闪点(°C)
152 °C - DIN 51758
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
其他客户在看
"Conductive monolithic catalysts: development and industrial pilot tests for the oxidation of o-xylene to phthalic anhydride"
Groppi G, et al.
Industrial & Engineering Chemistry Research, 51(22), 7590-7596 (2011)
Phthalic anhydride from o-xylene catalysis: science and engineering.
Nikolov V, et al.
Catalysis Reviews: Science and Engineering, 33(3-4), 319-374 (1991)
Xin Hai et al.
Electrophoresis, 31(19), 3352-3361 (2010-10-01)
A rapid and sensitive electrophoretically mediated microanalysis method with field-enhanced sample injection (FESI) for in-capillary derivatization was developed to determine selenomethionine (SeMet) and selenomethionine selenoxide (SeOMet). Phthalic anhydride (PA) was selected as the derivatization reagent due to the fast reaction
Yuichi Kajita et al.
Journal of the American Chemical Society, 130(51), 17226-17227 (2008-12-04)
An intermolecular nickel-catalyzed addition reaction has been developed where phthalic anhydrides react with alkynes to afford substituted isocoumarins. A mechanistic rationale is proposed, implying reductive elimination of Ni(0) promoted by ZnCl(2) cocatalyst as the key step of the catalytic cycle.
C J Sparham et al.
Journal of chromatography. A, 1062(1), 39-47 (2005-02-01)
A new method for the analysis of alcohol ethoxylates (AEs) using electrospray ionisation liquid chromatography/mass spectrometry (ESI LC/MS) is described. The procedure incorporates a novel derivatisation step with phthalic anhydride for the analysis of EO0-20 ethoxylates in a single analysis.
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