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Merck

125733

Sigma-Aldrich

邻苯二甲酸酐

ReagentPlus®, 99%

别名:

1,2-Benzenedicarboxylic anhydride, 1,3-Isobenzofurandione, Phthalic acid anhydride

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1 KG
$78.40
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$154.00
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$624.00

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1 KG
$78.40
2.5 KG
$154.00
16 KG
$624.00

About This Item

经验公式(希尔记法):
C8H4O3
CAS号:
分子量:
148.12
Beilstein:
118515
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

$78.40


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蒸汽密度

5.1 (vs air)

质量水平

蒸汽压

<0.01 mmHg ( 20 °C)

产品线

ReagentPlus®

方案

99%

表单

flakes

自燃温度

1058 °F

expl. lim.

10.4 %

沸点

284 °C (lit.)

mp

131-134 °C (lit.)

官能团

anhydride
ester

SMILES字符串

O=C1OC(=O)c2ccccc12

InChI

1S/C8H4O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h1-4H

InChI key

LGRFSURHDFAFJT-UHFFFAOYSA-N

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一般描述

Phthalic anhydride is an industrially important chemical. It can be prepared from o-xylene or naphthalene.[1] It is widely used for the industrial preparation of plasticizers for PVC (polyvinyl chloride).[2]
Phthalic anhydride can be synthesized via oxidation of o-xylene, in the presence of V2O5/TiO2 monolithic catalyst supported by aluminium honeycomb.[3]

应用

Phthalic anhydride may be used in the synthesis of the following compounds:

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

305.6 °F - DIN 51758

闪点(°C)

152 °C - DIN 51758

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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"Conductive monolithic catalysts: development and industrial pilot tests for the oxidation of o-xylene to phthalic anhydride"
Groppi G, et al.
Industrial & Engineering Chemistry Research, 51(22), 7590-7596 (2011)
Phthalic anhydride from o-xylene catalysis: science and engineering.
Nikolov V, et al.
Catalysis Reviews: Science and Engineering, 33(3-4), 319-374 (1991)
Xin Hai et al.
Electrophoresis, 31(19), 3352-3361 (2010-10-01)
A rapid and sensitive electrophoretically mediated microanalysis method with field-enhanced sample injection (FESI) for in-capillary derivatization was developed to determine selenomethionine (SeMet) and selenomethionine selenoxide (SeOMet). Phthalic anhydride (PA) was selected as the derivatization reagent due to the fast reaction
Yuichi Kajita et al.
Journal of the American Chemical Society, 130(51), 17226-17227 (2008-12-04)
An intermolecular nickel-catalyzed addition reaction has been developed where phthalic anhydrides react with alkynes to afford substituted isocoumarins. A mechanistic rationale is proposed, implying reductive elimination of Ni(0) promoted by ZnCl(2) cocatalyst as the key step of the catalytic cycle.
C J Sparham et al.
Journal of chromatography. A, 1062(1), 39-47 (2005-02-01)
A new method for the analysis of alcohol ethoxylates (AEs) using electrospray ionisation liquid chromatography/mass spectrometry (ESI LC/MS) is described. The procedure incorporates a novel derivatisation step with phthalic anhydride for the analysis of EO0-20 ethoxylates in a single analysis.

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