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Merck

24-2830

Sigma-Aldrich

三氯化磷

CP

别名:

氯化磷(III)

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About This Item

线性分子式:
PCl3
CAS号:
分子量:
137.33
Beilstein:
969177
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:

等级

CP

蒸汽密度

4.75 (vs air)

蒸汽压

100 mmHg ( 20 °C)
125 mmHg ( 25 °C)
385 mmHg ( 55 °C)

表单

liquid

存货情况

available only in Japan

dilution

(for analytical testing)

折射率

n20/D 1.5148 (lit.)

沸点

74-78 °C (lit.)

mp

−112 °C (lit.)

密度

1.574 g/mL at 20 °C (lit.)

SMILES字符串

ClP(Cl)Cl

InChI

1S/Cl3P/c1-4(2)3

InChI key

FAIAAWCVCHQXDN-UHFFFAOYSA-N

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警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation

靶器官

Respiratory Tract

补充剂危害

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Petri A Turhanen et al.
Organic & biomolecular chemistry, 1(18), 3223-3226 (2003-10-07)
Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from
Phosphorus trichloride-mediated and microwave-assisted synthesis of a small collection of amides bearing strong electron-withdrawing group substituted anilines.
Matteo Colombo et al.
Journal of combinatorial chemistry, 11(3), 335-337 (2009-03-31)
S Wason et al.
The American journal of medicine, 77(6), 1039-1042 (1984-12-01)
A railroad accident in Somerville, Massachusetts, led to spillage of phosphorus trichloride liquid. Attempted clean-up with water led to the liberation of phosphorus trichloride, phosphoric acid, hydrochloric acid, and phosphorus oxides. Seventeen people exposed to this mixture were studied. Patients
Núria Mont et al.
Molecular diversity, 13(1), 39-45 (2008-11-28)
A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, affords the corresponding 2-hydro-4-oxo-pyridopyrimidine 14, which is converted
[X-ray analysis of lung damage caused by PCl3 inhalation].
Chun-fang Li et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 23(4), 308-309 (2005-09-29)

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