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Merck

T81108

Sigma-Aldrich

1,3,5-三噁烷

≥99%

别名:

三氧杂环已烷, 三聚甲醛, 对称-三噁烷

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25 G
$33.70
100 G
$55.10
500 G
$70.80
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$246.00

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25 G
$33.70
100 G
$55.10
500 G
$70.80
2 KG
$246.00

About This Item

经验公式(希尔记法):
C3H6O3
CAS号:
分子量:
90.08
Beilstein:
102769
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$33.70


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质量水平

方案

≥99%

自燃温度

777 °F

expl. lim.

29 %

mp

59-62 °C (lit.)

SMILES字符串

C1OCOCO1

InChI

1S/C3H6O3/c1-4-2-6-3-5-1/h1-3H2

InChI key

BGJSXRVXTHVRSN-UHFFFAOYSA-N

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应用

1,3,5-三恶烷被广泛用作无水甲醛的来源。[1]
可用于合成:
  • 聚甲醛 [2] [3] 和超支化聚酯。[4]
  • 杯芳烃如杯[4]间苯二酚、杯[6]间苯二酚 [5] 和对--丁基杯[8]和[9]芳烃。[6]
  • 各种天然产物包括(-)-motuporin [7] , (+)-sundiversifolide [8] , (+)-lyconadin A 和 (-)-葡聚糖蛋白 B。[9]

警示用语:

Danger

危险声明

危险分类

Flam. Sol. 1 - Repr. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 1

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Enantioselective synthesis of the protein phosphatase inhibitor (−)-motuporin.
Hu T and Panek JS.
Journal of the American Chemical Society, 124(38), 11368-11378 (2002)
Cationic Copolymerization of 1, 3, 5-Trioxane with 1, 3-Dioxepane: A Comprehensive Approach to the Polyacetal Process.
Sharavanan K, et al.
Macromolecules, 42(22), 8702-8710 (2009)
Calix[6]resorcinarenes: the first examples of [1 6] metacyclophanes derived from resorcinols.
Konishi H, et al.
Journal of the Chemical Society. Chemical Communications, (3), 309-310 (1995)
Generation of orthorhombic polyoxymethylene in a cationic polymerization system of trioxane.
Iguchi M.
Polymer, 24(7), 915-920 (1983)
The Lyconadins: enantioselective total syntheses of (+)-lyconadin A and (−)-lyconadin B.
Beshore DC and Smith AB.
Journal of the American Chemical Society, 130(41), 13778-13789 (2008)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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