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Merck

O1858

Sigma-Aldrich

1-十八硫醇

98%

别名:

Mercaptan C18, 十八硫醇, 正十八硫醇

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25 ML
$73.20
100 ML
$166.00

About This Item

线性分子式:
CH3(CH2)17SH
CAS号:
分子量:
286.56
Beilstein:
1811934
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

$73.20


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质量水平

方案

98%

沸点

204-210 °C/11 mmHg (lit.)

mp

30-33 °C (lit.)

密度

0.847 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCCCCCCCCCCCCCCS

InChI

1S/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

InChI key

QJAOYSPHSNGHNC-UHFFFAOYSA-N

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一般描述

1-十八硫(ODT)是一种具有长碳链的烷烃硫醇,主要用作各种材料表面改性的自组装单分子膜(SAM),其兼具高润湿性和低表面能,具有优异的超疏水性。[1][2]

应用

ODT可用于对纳金米(AuNPs)/镍(Ni)泡沫镍复合物进行表面改性,制备用于检测有机污染物的3D表面增强拉曼光谱(SERS)衬底。[3]此外,它还可用于增强纳米级铜膜、[4]石墨烯和二氧化硅等不同材料的超疏水性能,以用于汞检测和电化学分析等不同应用。[5][1]

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Aquatic Acute 1 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Three-dimensional superhydrophobic surface-enhanced Raman spectroscopy substrate for sensitive detection of pollutants in real environments.
Zhao H, et al.
Journal of Material Chemistry A, 3(8), 4330-4337 (2015)
Fabrication of super-hydrophobic nano-sized copper films by electroless plating.
Liu X, et al.
Thin Solid Films, 518(14), 3731-3734 (2010)
Electrochemical investigation of dynamic interfacial processes at 1-octadecanethiol-modified copper electrodes in halide-containing solutions.
Ma HY, et al.
Electrochimica Acta, 48(28), 4277-4289 (2003)
David Wakerley et al.
Nature materials, 18(11), 1222-1227 (2019-08-07)
The aqueous electrocatalytic reduction of CO2 into alcohol and hydrocarbon fuels presents a sustainable route towards energy-rich chemical feedstocks. Cu is the only material able to catalyse the substantial formation of multicarbon products (C2/C3), but competing proton reduction to hydrogen
Ken Kobayashi et al.
Journal of chromatography. A, 1110(1-2), 95-101 (2006-02-14)
Three types of thiol compounds (n-octadecanethiol, thiophenol, and 2-phenylethanethiol) were used to modify the gold-coated polystyrene particles (dp. 5microm) to prepare a stationary phase for capillary liquid chromatography through the formation of self-assembled monolayer. The column with n-octadecanethiol-modified gold-coated polystyrene

商品

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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