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Merck

471364

Sigma-Aldrich

1-十二烷硫醇

1-Dodecanethiol

≥98%

别名:

1-巯基代十二烷, NDM, 十二硫醇, 月桂硫醇, 正十二硫醇

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100 ML
$65.60
500 ML
$106.00
2 L
$117.60
18 L
$934.00

$65.60


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100 ML
$65.60
500 ML
$106.00
2 L
$117.60
18 L
$934.00

About This Item

线性分子式:
CH3(CH2)11SH
CAS号:
分子量:
202.40
Beilstein:
969337
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

$65.60


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蒸汽密度

7 (vs air)

品質等級

化驗

≥98%

折射率

n20/D 1.459 (lit.)

bp

266-283 °C (lit.)

密度

0.845 g/mL at 25 °C (lit.)

SMILES 字串

CCCCCCCCCCCCS

InChI

1S/C12H26S/c1-2-3-4-5-6-7-8-9-10-11-12-13/h13H,2-12H2,1H3

InChI 密鑰

WNAHIZMDSQCWRP-UHFFFAOYSA-N

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相关类别

一般說明

1-十二烷硫醇(DDT)是可形成自组装单层膜(SAM)的烷基硫醇,可用作具有平衡理化性质的有机硫醇源。[1]

應用

DDT可用作合成CdS量子点(QD)和硫化铅纳米颗粒(PbS)的硫醇来源,可能应用于节能照明、太阳能电池和铵气传感剂。[2][3][4]这种成分可用于在铜表面形成自组装单层膜(SAM),充当耐腐蚀涂层。[5]DDT官能化可能会在锗(Ge)上形成SAM,从而改善未来微电子学应用的表面特性。[6]
该分子可用于生产疏水性SAM。此外,它还可用于混合SAM,以提供疏水性背景,并充当拉大与其他官能团或结构域距离的间隔臂。[7]

訊號詞

Danger

危險聲明

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1A

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

262.4 °F - closed cup

閃點(°C)

128 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Slide 1 of 1

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Do Young Kim et al.
Polymers, 12(9) (2020-09-10)
The extreme elasticity and reversible deformability of rubber, which is one of the most versatile polymers in modern society, is dependent on several factors, including the processing conditions, curing system, and types of additives used. Since the rubber's mechanical properties
Chemical synthesis and optical characterization of regular and magic-sized CdS quantum dot nanocrystals using 1-dodecanethiol.
Dickson R and Hu M
Journal of Materials Research, 30(7), 890-895 (2015)
Inhibition Effect of 3D Nanostructures on the Corrosion Resistance of 1-Dodecanethiol Self-Assembled Monolayers on Copper in Nacl Solution.
Shuai Hm et al.
Materials, 8(10), 11661-11679 (2018)
Functions of 1-Dodecanethiol in the Synthesis and Post-treatment of Copper Sulfide Nanoparticles Relevant to Their Photocatalytic Applications.
Lihui C and Guohua L
ACS Applied Nano Materials, 1(9), 4587?4593-4587?4593 (2018)
Marta Gambucci et al.
Soft matter, 15(32), 6571-6580 (2019-08-01)
The comprehension and control of the interactions between nanoparticles and proteins at a molecular level are crucial to improve biomedical applications of nanomaterials and to develop nanosystems able to influence and regulate the conformational changes in proteins. In this work

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纳米颗粒的溶剂热合成:从纳米电路、纳米光学电路到纳米磁学和生物技术应用。

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Questions

1–3 of 3 Questions  
  1. How do you coat copper foil with a single layer of 1-Dodecanethiol molecules on one surface only. Shielding the other surface with a tape does not work, because removing the tape can bend the foil and damage the coating.

    1 answer
    1. Following surface preparation and oxidation removal, a solution of 1-Dodecanethiol in a suitable solvent, such as toluene or ethanol, should be prepared at a concentration typically between 1 and 10 mM. To achieve selective coating on one surface, a physical mask (e.g., tape or a polymer film) can be used to cover the areas of the copper foil that are not to be coated before immersing it in the 1-Dodecanethiol solution. Alternatively, a drop casting method can be used, whereby a drop of the 1-Dodecanethiol solution would be applied directly onto the desired surface and it would be allowed to spread out evenly. This method requires careful control to avoid spreading to the other side. The copper foil should then be immersed in the solution for a specified time (typically several hours) to allow the 1-Dodecanethiol molecules to self-assemble onto the exposed surface. After the desired time, the copper foil should be removed and rinsed gently with the same solvent used for the solution to remove any unbound thiol molecules.

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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