L511838

[Ir(dtbbpy)(ppy)₂][PF₆]

Aldrich^CPR

• 经验公式（希尔记法）: C₄₀H₄₀F₆IrN₄P
• CAS号: 676525-77-2
• 分子量: 913.95
• UNSPSC代码: 12352200
• PubChem化学物质编号: 329817539

属性

• 反应适用性: reagent type: catalyst; reaction type: C-H Activation
• SMILES字符串: CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
• InChI: 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
• InChI key: DZARMRZNOUWGQE-UHFFFAOYSA-N

说明

应用

Catalyst for the visible-light mediated formation of alpha-amino radicals, used by Nishibayashi for addition into electron-poor alkenes and imines

Visible-Light-Mediated Utilization of ·-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

In presence of [Co(bpy)₃]²⁺, serves as photosensitizer for H₂ generation from water (water splitting).

Tricyclometalated Iridium Complexes as Highly Stable Photosensitizers for Light-Induced Hydrogen Evolution

For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis

其他说明

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

安全信息

• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable