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C31104

Sigma-Aldrich

3-氯-2-氯甲基-1-丙烯

99%

别名:

1,1-双（氯甲基）乙烯, 甲代烯丙基二氯

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$791.00

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10 G
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About This Item

线性分子式:
CH2=C(CH2Cl)2
CAS号:
1871-57-4
分子量:
125.00
Beilstein:
1560178
EC 号:
217-489-3
MDL编号:
MFCD00000952
UNSPSC代码:
12352100
PubChem化学物质编号:
24892333
NACRES:
NA.22

$259.00

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蒸汽密度

3.12 (vs air)

方案

99%

表单

liquid

自燃温度

896 °F

expl. lim.

8.1 %

折射率

n20/D 1.4753 (lit.)

沸点

138 °C (lit.)

mp

−14 °C (lit.)

密度

1.08 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

ClCC(=C)CCl

InChI

1S/C4H6Cl2/c1-4(2-5)3-6/h1-3H2

InChI key

XJFZOSUFGSANIF-UHFFFAOYSA-N

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应用

3-氯-2-氯甲基-1-丙烯可用于合成 2,11-双（亚甲基）精胺、精胺氧化酶的抑制剂[1]和共轭聚合物的支链侧链。[2][3]它也可用于(−)-诱杀烯醇全合成过程中的分子间[2+2]光环加成反应。 [4]

象形图

FlameSkull and crossbones
GHS02,GHS06

警示用语：

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

96.8 °F

闪点(°C)

36 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBK7646
STBK9727
STBK1912
STBH9604
STBH7209

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Synthesis of 2, 11-bis (methylidene) spermine, a new inhibitor of spermine oxidase.
Grigorenko N A, et al.
Russian Journal of Bioorganic Chemistry, 42(4), 423-427 (2016)
Synthesis of well-defined three-and four-armed cage-shaped polymers via ?topological conversion? from trefoil-and quatrefoil-shaped polymers.
Satoh Y, et al.
Macromolecules, 50(1), 97-106 (2016)
Diketopyrrolopyrrole?based Conjugated Polymers Bearing Branched Oligo (Ethylene Glycol) Side Chains for Photovoltaic Devices.
Chen X, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 128(35), 10532-10536 (2016)
Enantioselective Intermolecular [2+ 2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol.
Poplata S and Bach T
Journal of the American Chemical Society, 140(9), 3228-3231 (2018)
Matthew K McBride et al.
Science advances, 4(8), eaat4634-eaat4634 (2018-08-29)
Liquid crystalline (LC) elastomers (LCEs) enable large-scale reversible shape changes in polymeric materials; however, they require intensive, irreversible programming approaches in order to facilitate controllable actuation. We have implemented photoinduced dynamic covalent chemistry (DCC) that chemically anneals the LCE toward

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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