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Merck

A71301

Sigma-Aldrich

2-氨基苯酚

99%

别名:

(2-羟苯基)胺, 1-羟基-2-氨基苯, 2-氨基-1-羟基苯, 2-氨基苯基乙醇, 2-氨基苯酚, 2-羟基苯胺, 2-羟苯胺, o-氨基羟基苯, o-羟基苯胺, o-羟苯胺

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5 G
$53.20
100 G
$62.00
500 G
$173.00

$53.20


国内现货,预计发货时间2025年4月21日详情


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5 G
$53.20
100 G
$62.00
500 G
$173.00

About This Item

线性分子式:
H2NC6H4OH
CAS号:
分子量:
109.13
Beilstein:
606075
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$53.20


国内现货,预计发货时间2025年4月21日详情


获取大包装报价

质量水平

方案

99%

表单

powder

mp

170-175 °C (lit.)

SMILES字符串

Nc1ccccc1O

InChI

1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

InChI key

CDAWCLOXVUBKRW-UHFFFAOYSA-N

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应用

2-氨基苯酚可用于合成:
  • 与β氨基醇在Pd/C-I2催化下通过氧化环羰基化反应合成2-噁唑烷酮衍生物。[1]
  • 与亚水杨基-4-氨基安替比林合成席夫碱过渡金属(II)配合物。[2]
  • 在富氧气氛、活性碳催化下与醛合成2-芳基苯并噁唑。[3]

象形图

Health hazardExclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

闪点(°F)

334.4 °F - closed cup

闪点(°C)

168 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Bifu Liu et al.
Chemical communications (Cambridge, England), 48(93), 11446-11448 (2012-10-23)
A robust route to 4-amine-benzo[b][1,4]oxazepines relying upon a palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides has been developed. This chemistry presumably proceeds through the migratory insertion of isocyanides into the vinyl-palladium intermediate as a key step.
Anangamohan Panja et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 5068-5075 (2013-02-12)
A bis(imido)-bridged dinuclear cobalt(III) complex, [Co2(amp)2(μ-imp)2Cl2]Cl2·2H2O () [amp = 2-aminomethylpyridine; imp = 2-iminomethylpyridine anion], was synthesized by the reaction of cobalt(II) chloride with 2-aminomethylpyridine in the presence of alkaline hydrogen peroxide at room temperature. X-ray crystallography reveals that both the
Ru Chen et al.
Organic & biomolecular chemistry, 9(22), 7675-7679 (2011-09-23)
A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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